A Highly Efficient Mononuclear Iridium Complex Photocatalyst for CO2 Reduction under Visible Light

被引：297

作者：

Sato, Shunsuke ^{[1
,2
]}

Morikawa, Takeshi ^{[1
]}

Kajino, Tsutomu ^{[1
]}

Ishitani, Osamu ^{[3
,4
]}

机构：

[1] Toyota Cent Res & Dev Labs Inc, Nagakute, Aichi 4801192, Japan

[2] Japan Sci & Technol Agcy JST, Precursory Res Embryon Sci & Technol PRESTO, Kawaguchi, Saitama 3320012, Japan

[3] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Chem, Meguro Ku, Tokyo 1528551, Japan

[4] Tokyo Inst Technol, Grad Sch Sci & Engn, Dept Chem & Mat Sci, Meguro Ku, Tokyo 1528551, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 03期

关键词：

coordination modes; CO2; reduction; homogeneous catalysis; iridium; photocatalysis; RHENIUM(I) COMPLEXES; WATER REDUCTION; CARBON-DIOXIDE; AQUEOUS-MEDIA; CONVERSION; COBALT; ELECTROCATALYST; GENERATION; FORMATE; SYSTEM;

D O I：

10.1002/anie.201206137

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mononuclear iridium(III) terpyridine (tpy) 2-phenylpyridine (ppy) complexes [Ir(tpy)(R-ppy)Cl] (R=H, Me, CF3) can act as efficient and selective CO2 reduction photocatalysts. The reaction is driven using visible light in a homogeneous solution, and even in a H2O mixed solution. The most efficient photocatalyst is [Ir(tpy)(Me-ppy)Cl], for which the turnover in CO was over 50 and the quantum yield was 0.21 at 480 nm. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：988 / 992

页数：5

共 50 条

[21] CO2 reduction using oxynitrides and nitrides under visible light
Maeda, Kazuhiko
PROGRESS IN SOLID STATE CHEMISTRY, 2018, 51 : 52 - 62
[22] Highly Efficient Electrocatalytic Reduction of CO2 to CO by a Molecular Chromium Complex
Hooe, Shelby L.
Dressel, Julia M.
Dickie, Diane A.
Machan, Charles W.
ACS CATALYSIS, 2020, 10 (02) : 1146 - 1151
[23] Photocatalytic CO2 Reduction of Au/Cu2O@Au Photocatalyst Under Visible-Light Irradiation
Zhang, Rui
Qi, Zhong
Shi, Junjun
He, Jie
Shiyou Xuebao, Shiyou Jiagong/Acta Petrolei Sinica (Petroleum Processing Section), 2023, 39 (05): : 1092 - 1103
[24] A core-satellite structured type II heterojunction photocatalyst with enhanced CO2 reduction under visible light
Cheng, Yuanyuan
Liu, Yixian
Liu, Yunliang
Li, Yaxi
Wu, Ruqiang
Du, Yongchao
Askari, Najmeh
Liu, Naiyun
Qiao, Fen
Sun, Chenghua
Kang, Zhenhui
Li, Haitao
NANO RESEARCH, 2022, 15 (10) : 8880 - 8889
[25] A core-satellite structured type II heterojunction photocatalyst with enhanced CO2 reduction under visible light
Yuanyuan Cheng
Yixian Liu
Yunliang Liu
Yaxi Li
Ruqiang Wu
Yongchao Du
Najmeh Askari
Naiyun Liu
Fen Qiao
Chenghua Sun
Zhenhui Kang
Haitao Li
Nano Research, 2022, 15 : 8880 - 8889
[26] A hexanuclear cobalt metal-organic framework for efficient CO2 reduction under visible light
Zhao, Jiao
Wang, Qi
Sun, Chunyi
Zheng, Tiantian
Yan, Likai
Li, Mengting
Shao, Kuizhan
Wang, Xinlong
Su, Zhongmin
JOURNAL OF MATERIALS CHEMISTRY A, 2017, 5 (24) : 12498 - 12505
[27] Highly efficient electrocatalytic CO2 reduction by a CrIII quaterpyridine complex
Wang, Jia- Wei
Luo, Zhi- Mei
Yang, Guangjun
Gil-Sepulcre, Marcos
Kupfer, Stephan
Ruediger, Olaf
Ouyang, Gangfeng
PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2024, 121 (14)
[28] A nature inspired molecular Ni-catalyst for efficient photocatalytic CO2 reduction to CO under visible light
Qing He
Bin Wu
Yongpan Hu
Wei Huang
Yanguang Li
Science China Chemistry, 2020, 63 : 1716 - 1720
[29] A nature inspired molecular Ni-catalyst for efficient photocatalytic CO2 reduction to CO under visible light
Qing He
Bin Wu
Yongpan Hu
Wei Huang
Yanguang Li
Science China(Chemistry), 2020, (12) : 1716 - 1720
[30] Selective reduction of CO2 by conductive MOF nanosheets as an efficient co-catalyst under visible light illumination
Zhu, Wei
Zhang, Chufeng
Li, Qin
Xiong, Likun
Chen, Rongxiang
Wan, Xiaobing
Wang, Zhen
Chen, Wei
Deng, Zhao
Peng, Yang
APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 238 : 339 - 345

← 1 2 3 4 5 →