Preparation and Characterization of Activated Carbons from Oxygen-rich Lignite for Electric Double-layer Capacitor

被引:19
|
作者
Zhao, Xiao-Yan [1 ]
Wu, Yan [1 ]
Cao, Jing-Pei [1 ]
Zhuang, Qi-Qi [1 ]
Wan, Xiao [1 ]
He, Shan [1 ]
Wei, Xian-Yong [1 ]
机构
[1] China Univ Min & Technol, Key Lab Coal Proc & Efficient Utilizat, Minist Educ, Xuzhou 221116, Jiangsu, Peoples R China
来源
关键词
Activated carbons; Oxygen-rich lignite; Electric double-layer capacitor; HIGH-PERFORMANCE SUPERCAPACITORS; PORE-SIZE DISTRIBUTION; KOH ACTIVATION; POROUS CARBONS; ENERGY-STORAGE; ELECTROCHEMICAL CAPACITORS; GRAPHENE NANOSHEETS; CATALYST; CONDUCTIVITY; NANOFIBERS;
D O I
10.20964/2018.03.50
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Activated carbons (ACs) were derived from oxygen-rich lignite via chemical activation for electric double-layer capacitor (EDLC). The preparation parameters affect the pore structure and specific surface area of ACs were discussed in this work. The pores of the ACs are mainly micropores and the functional groups of ACs are not changed compared with SL. When the carbonized temperature is 700 degrees C, activated temperature is 800 degrees C and KOH/char ratio is 4, the AC is rich in C-O, C=O and -COOH species, exhibits excellent electrochemical performance with the maximum specific capacitance of 213 F g(-1) in 6 M KOH at the current density of 40 mA g(-1). Furthermore, the electrode exhibits excellent cycle stability. Therefore, the AC electrodes derived from lignite are promising candidates for EDLC.
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页码:2800 / 2816
页数:17
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