Occurrence of Bisphenol A, Estrone, 17β-Estradiol and 17α-Ethinylestradiol in Portuguese Rivers

被引:49
|
作者
Rocha, Sonia [1 ]
Domingues, Valentina F. [2 ,3 ]
Pinho, Carina [4 ]
Fernandes, Virginia C. [2 ,5 ]
Delerue-Matos, Cristina [2 ]
Gameiro, Paula [1 ]
Mansilha, Catarina [6 ,7 ]
机构
[1] Univ Porto, Fac Ciencias, REQUIMTE, P-4169007 Oporto, Portugal
[2] Inst Politecn Porto, Inst Super Engn, REQUIMTE, P-4200072 Oporto, Portugal
[3] Inst Super Engn Porto, Dept Quim, P-4200072 Oporto, Portugal
[4] Univ Porto, Fac Farm, REQUIMTE, P-4050047 Oporto, Portugal
[5] Univ Porto, Fac Ciencia, Dept Quim, CIQ, P-4169007 Oporto, Portugal
[6] Inst Nacl Saude, P-4000055 Oporto, Portugal
[7] Univ Porto, REQUIMTE, Oporto, Portugal
关键词
River water; Estrogens; Bisphenol-A; endocrine disruptors; ENDOCRINE-DISRUPTING COMPOUNDS; WATER; PHARMACEUTICALS; CHROMATOGRAPHY; CONTAMINANTS; ESTROGENS; STREAMS;
D O I
10.1007/s00128-012-0887-1
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
This study focused on the occurrence of several EDCs including bisphenol A, estrone (E1), the 17 beta-estradiol (E2) and 17 alpha-ethinylestradiol (EE2) in fourteen rivers of Portugal. Samples analysis revealed a widespread contamination of BPA especially in Ave, Cavado, Douro, Ferro, Sousa and Vizela Rivers. Achieving 98.4 ng/L for the highest concentration. The estrogens achieved above the method quantification limit (MQL) were E1 in Agueda River and E2 in Ave, Lima and TA cent mega Rivers. The maximum concentration detected for E1 was 26.9 ng/L. EE2 was detected only below MQL.
引用
收藏
页码:73 / 78
页数:6
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