A new polymorph of HMTD

被引：3
|
作者：
McLennan, Lindsay [1 ]
Smith, James L. [1 ]
Oxley, Jimmie C. [1 ]
机构：
[1] Univ Rhode Isl, Dept Chem, Kingston, RI 02881 USA
来源：
JOURNAL OF ENERGETIC MATERIALS | 2021年 / 39卷 / 03期
关键词：
Hexamethylene triperoxide diamine (HMTD); polymorph; peroxide; HEXAMETHYLENE TRIPEROXIDE DIAMINE; DENSITY-FUNCTIONAL THEORY; TRIACETONE TRIPEROXIDE; RAMAN; SPECTROSCOPY; CONFORMERS; TATP;
D O I：
10.1080/07370652.2020.1802630
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
While exploring the synthesis pathway of HMTD, an unexpected new route for preparing HMTD was found through the reaction of formaldehyde, hydrogen peroxide, and ammonium hydroxide. The recovered HMTD was characterized by Raman spectroscopy and powder x-ray diffraction and found to be a different crystal structure. This HMTD is believed to be the result of a different conformation of the HMTD, only previously predicted by computational methods and through the use of specialized NMR reagents.
引用
收藏
页码：361 / 376
页数：16
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