Analytical Approach for Evaluation of Lithium-Ion Battery Cells

被引:5
|
作者
Wagner, Sebastian [1 ,2 ]
Oberland, Alexander [2 ,3 ]
Turek, Thomas [1 ,2 ]
机构
[1] Tech Univ Clausthal, Inst Chem & Electrochem Proc Engn, Leibnizstr 17, D-38678 Clausthal Zellerfeld, Germany
[2] Energie Forschungszentrum Niedersachsen EFZN, Stollen 19A, D-38640 Goslar, Germany
[3] Tech Univ Clausthal, Inst Elect Power Engn & Energy Syst, Leibnizstr 28, D-38678 Clausthal Zellerfeld, Germany
关键词
batteries; chemical reaction engineering; dimensionless modeling; lithium; manganese; OPTIMIZATION; DESIGN; SIMULATION; INTERCALATION; INSERTION;
D O I
10.1002/ente.201600137
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
A new method for evaluation of battery cells containing porous thin-layer electrodes is developed. For this purpose, a typical concept of chemical reaction engineering to classify reactors by dimensionless characteristic values is used. Therefore, the system of equations describing the porous electrodes in a battery cell is transferred to dimensionless notation and corresponding dimensionless properties are developed. The required kinetic data are measured with the help of electrochemical test cells. A complete set of parameters for the description of the lithium-ion battery is determined and the characteristic properties for the chosen example are calculated and analyzed. Finally, the performance of the anode and cathode using lithium manganese oxide and surface-modified graphite as active materials is compared with the aid of the newly developed dimensionless parameters.
引用
收藏
页码:1543 / 1549
页数:7
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