Rare earth thiocyanate complexes with 18-crown-6 co-ligands

被引：7
|
作者：
Bakker, Jacinta M. [1 ]
Deacon, Glen B. [1 ]
Junk, Peter C. [1 ]
机构：
[1] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
来源：
POLYHEDRON | 2013年 / 52卷
关键词：
Lanthanoids; Rare earths; Thiocyanates; Crown ethers; CROWN-ETHER COMPLEXES; CRYSTAL-STRUCTURE; LANTHANIDE(III) COMPLEXES; IONIC-RADII; SERIES;
D O I：
10.1016/j.poly.2012.08.028
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of [Ln(NCS)(3)(THF)(4)](2) or [Yb(NCS)(3)(THF)(4)] with 18-crown-6 yields the moisture-stable [Ln(NCS)(3)(18-crown-6)] (Ln = La, Nd, Dy, Yb) complexes. Although the Ln contraction does not affect the coordination number, the crown ether is decreasingly folded with decreasing ion size. (C) 2012 Elsevier Ltd. All rights reserved.
引用
下载
收藏
页码：560 / 564
页数：5
相关论文
共 50 条
  • [21] Thallium(18-crown-6) hexafluorophosphate, [Tl(18-crown-6)](PF6)
    Liu, FH
    APPLIED ORGANOMETALLIC CHEMISTRY, 2003, 17 (09) : 737 - 738
  • [22] TETRAPHENYLBORATES OF DIVALENT LANTHANIDE COMPLEXES WITH THE POLYETHER 18-CROWN-6
    KULYUKHIN, SA
    MIKHEEV, NB
    VELESHKO, IE
    AUERMAN, LN
    SOVIET RADIOCHEMISTRY, 1992, 34 (02): : 173 - 180
  • [23] Study on complexes of trihydrated praseodymium perchlorate with 18-crown-6
    Xue, GL
    Li, QD
    Hu, SM
    Xu, H
    Ren, DH
    ACTA CHIMICA SINICA, 1996, 54 (06) : 568 - 574
  • [24] ELECTRON-DENSITY STUDIES ON COMPLEXES OF 18-CROWN-6
    KNOCHEL, A
    HAARICH, A
    LUGER, P
    KORITSANSZKY, T
    BUSCHMANN, J
    ZOBEL, D
    PURE AND APPLIED CHEMISTRY, 1993, 65 (03) : 503 - 509
  • [25] ON THE SOLID-STATE CONFORMATIONS OF 18-CROWN-6 COMPLEXES
    FYLES, TM
    GANDOUR, RD
    JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1992, 12 (1-4): : 313 - 332
  • [26] Supramolecular assemblages from uranyl complexes of calixarenes and potassium complexes of 18-crown-6 or dibenzo-18-crown-6
    Thuery, Pierre
    Masci, Bernardo
    Takimoto, Masashi
    Yamato, Takehiko
    INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (07) : 795 - 799
  • [27] LUMINESCENCE OF DIVALENT EUROPIUM COMPLEXES WITH 18-CROWN-6 DERIVATIVES
    ADACHI, GY
    SORITA, K
    KAWATA, K
    TOMOKIYO, K
    SHIOKAWA, J
    INORGANICA CHIMICA ACTA-F-BLOCK ELEMENTS ARTICLES AND LETTERS, 1985, 109 (02): : 117 - 121
  • [28] COMPLEXES OF LANTHANOID SALTS WITH MACROCYCLIC LIGANDS .10. COMPLEXES OF LANTHANOID NITRATES WITH 15-CROWN-5 AND 18-CROWN-6 ETHERS
    BUNZLI, JCG
    WESSNER, D
    HELVETICA CHIMICA ACTA, 1981, 64 (02) : 582 - 598
  • [29] Vibrational study of isolated 18-crown-6 ether complexes with alkaline-earth metal cations
    Gamez, Francisco
    Hurtado, Paola
    Martinez-Haya, Bruno
    Berden, Giel
    Oomens, Jos
    INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2011, 308 (2-3) : 217 - 224
  • [30] Molar conductance of the complexes of 18-crown-6 with alkaline earth metal ions in methanol plus water
    Sway, MI
    Samara, N
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1999, 44 (02): : 343 - 348
12345