Controllable one-step synthesis of spirocycles, polycycles, and di- and tetrahydronaphthalenes from aryl-substituted propargylic alcohols

被引：59

作者：

Huang, Wen ^{[1
]}

Zhen, Pengzhi ^{[1
]}

Zhang, Zhengxing ^{[1
]}

Liu, Ruiting ^{[1
]}

Chen, Zhenxia ^{[1
]}

Zhou, Xigeng ^{[1
,2
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

[2] State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 17期

关键词：

D O I：

10.1021/jo801210n

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel, convenient, and efficient method has been developed for selective synthesis of spirocycle, polycycle, and di- and tetrahydronaphthalene systems from aryl-substituted propargylic alcohols by FeCl(3)- or TsOH-catalyzed multiple activations of unsaturated C-C bonds and C-H bonds.

引用

页码：6845 / 6848

页数：4

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