Self-assembly of a three-dimensional supramolecular structure based on carboxyl-bridged tetrameric water clusters

被引：2
|
作者：
Meng, Fayan [1 ]
Jiao, Yuanhong [1 ]
Chen, Xuemei [1 ]
Teng, Lei [1 ]
机构：
[1] Huangshi Inst Technol, Sch Chem & Mat Engn, Huangshi 435003, Peoples R China
来源：
JOURNAL OF CHEMICAL RESEARCH | 2008年 / 10期
关键词：
water cluster; carboxyl-bridges; hydrogen bonds; thermogravimetric analysis;
D O I：
10.3184/030823408X361093
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A self-assembled, tetrameric water cluster stabilised by carboxyl-bridging has been characterised by X-ray diffraction studies and thermogravimetric analysis. Every water cluster is connected strongly via hydrogen bonds to four carboxyl oxygens of a terephthalate anion. The water rings are stable at room temperature, but when thermally decomposed, the water loss is irreversible.
引用
收藏
页码：584 / 586
页数：3
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