Some structural features of alkali aluminofluorophosphate glasses

被引：0

作者：

Smirnova, EV ^{[1
]}

Stepanov, SA ^{[1
]}

Urusovskaya, IB ^{[1
]}

Urusovskaya, LN ^{[1
]}

机构：

[1] All Russia Res Ctr, SI Vavilov State Opt Inst, St Petersburg 193171, Russia

来源：

GLASS PHYSICS AND CHEMISTRY | 1999年 / 25卷 / 03期

关键词：

D O I：

暂无

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Glasses of compositions (mol %) 50NaPO(3) . 20AlF(3) . 30LiF and 50NaPO(3) . 25AlF(3) . 25LiF are synthesized. It is elucidated how the AlF3 content affects the glass properties (density rho, refractive index n(e), linear thermal expansion coefficient a, and glass transition temperature Tg) and IR spectra. Analysis of the glass properties and IR spectra at different compositions demonstrates that the structure of the studied glasses is based on the [PO4](3-), [P2O7](4-), [PO3F](2-), and [AlF6](3-) groupings. The substitution of AlF3 for LiF results in a more closely packed arrangement of structural elements and an increase in the number of pyrophosphate, [AlF6](3-), and [PO3F](2-) groupings. It is revealed that the IR spectra of the studied glasses are similar in character.

引用

页码：254 / 256

页数：3

共 50 条

[41] Structural evidence of mixed alkali effect for aluminoborosilicate glasses
Hyun, Sung-Hee
Yeo, Tae-Min
Ha, Hong-Min
Cho, Jung-Wook
JOURNAL OF MOLECULAR LIQUIDS, 2022, 347
[42] A STRUCTURAL INTERPRETATION OF THE DENSITY OF ALKALI SILICATE-GLASSES
GASKELL, PH
JOURNAL DE PHYSIQUE, 1982, 43 (NC-9): : 101 - 105
[43] DC conductivity in some alkali doped vanadotellurite glasses
Kumar, M. Prashant
Sankarappa, T.
SOLID STATE IONICS, 2008, 178 (33-34) : 1719 - 1724
[44] Specific features of halogen binding in binary alkali silicate glasses
A. A. Kiprianov
E. A. Pyatina
I. S. Ivanovskaya
Glass Physics and Chemistry, 2008, 34 : 519 - 526
[45] Specific Features of Halogen Binding in Binary Alkali Silicate Glasses
Kiprianov, A. A.
Pyatina, E. A.
Ivanovskaya, I. S.
GLASS PHYSICS AND CHEMISTRY, 2008, 34 (05) : 519 - 526
[46] Special features of electric conductivity of alkali-silicate glasses
Samotejkin, V.V.
Gladushko, O.A.
Steklo i Keramika, 2002, (01): : 7 - 9
[47] Structural features of lead iron phosphate glasses
Reis, ST
Faria, DLA
Martinelli, JR
Pontuschka, WM
Day, DE
Partiti, CSM
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2002, 304 (1-3) : 188 - 194
[48] Structural features of hafnium iron phosphate glasses
Karabulut, M.
Yuksek, M.
Marasinghe, G. K.
Day, D. E.
JOURNAL OF NON-CRYSTALLINE SOLIDS, 2009, 355 (31-33) : 1571 - 1573
[49] Structure of binary alkali silicate glasses -: structural modifications caused by various alkali ions
Machácek, J
Gedeon, O
PHYSICS AND CHEMISTRY OF GLASSES, 2003, 44 (04): : 308 - 312
[50] Structural relaxation of density (as length) and electrical conductivity of some silicate glasses within of their glass transition regions .1. Alkali silicate glasses
Startsev, YK
Safutina, TV
Tarakanov, SV
FUNDAMENTALS OF GLASS SCIENCE AND TECHNOLOGY 1997, 1997, : 691 - 697

← 1 2 3 4 5 →