Reactive processing of particulate filled polymers:: m-phenylene bismaleimide modified polyethylene magnesium hydroxide composites

被引：13

作者：

Khunová, V ^{[1
]}

Hurst, J ^{[1
]}

Liauw, C ^{[1
]}

机构：

[1] Slovak Univ Technol Bratislava, Fac Chem Technol, Dept Plast & Rubber, SR-81237 Bratislava, Slovakia

来源：

POLYMER BULLETIN | 1999年 / 42卷 / 04期

关键词：

D O I：

10.1007/s002890050489

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The influence of processing temperature and the presence of the reactive modifier, m-phenylene bismaleimide (BMI), on the formation of highly filled polyethylene/Mg(OH)(2) composites has been investigated using central composite design methods. Infrared spectroscopic and differential scanning calorimetric evidence produced suggests that maleimide C=C bonds are involved in a free radically induced process which leads to extended and crosslinked polyethylene chains being produced, some of which encapsulate the filler particles, resulting in formation of a crosslinked interphase. This effect resulted in increased tensile strength and reduced composite melt flow rate (MFR).

引用

页码：457 / 463

页数：7