Post-Synthetic Modification of Zirconium Metal-Organic Frameworks for Adsorption and Separation of Light Hydrocarbons

被引：12
|
作者：
He, Huihui [1 ,2 ]
Guo, Bingbing [3 ]
Liu, Yang [1 ,2 ]
Zhang, Liangliang [1 ,2 ]
Huang, Wei [1 ,2 ]
机构：
[1] Shaanxi Inst Flexible Elect SIFE, Frontiers Sci Ctr Flexible Elect FSCFE, Xian 710072, Peoples R China
[2] Northwestern Polytech Univ, Shaanxi Inst Biomed Mat & Engn SIBME, Xian 710072, Peoples R China
[3] China Univ Petr East China, Sch Mat Sci & Engn, Key Lab Unconvent Oil & Gas Dev, Minist Educ, Qingdao 266580, Shandong, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2020年 / 20卷 / 08期
基金：
中国国家自然科学基金;
关键词：
ONE-POT SYNTHESIS; MOFS;
D O I：
10.1021/acs.cgd.0c00690
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Different functionalization of MOFs can lead to different structure-activity relationships. Flexible ligands make it easier and more diverse to assemble MOFs. The auxiliary ligand fumarate (FA) was inserted successfully into PCN-207 because of the flexibility of the primary linker and unsaturated Zr-6 cluster via the post-modification method. Moreover, the successfully synthesized (4,10)-connected stable PCN-207-FA exhibited excellent thermal/chemical stability and better adsorption/separation performance of light hydrocarbons than that of PCN-207 and PCN-207-BDC, which provide guidance for inserting multiple ligands into MOFs and reveal the importance of structure-activity relationships.
引用
收藏
页码：4882 / 4885
页数：4
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