Post-Synthetic Modification of Tagged Metal-Organic Frameworks

被引：253
|
作者：
Burrows, Andrew D. [1 ]
Frost, Christopher G. [1 ]
Mahon, Mary F. [1 ]
Richardson, Christopher [1 ]
机构：
[1] Univ Bath, Dept Chem, Bath BA2 7AY, Avon, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 44期
关键词：
metal-organic frameworks; microporous materials; post-synthetic modification; X-ray diffraction; zinc;
D O I：
10.1002/anie.200802908
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Playing tag with MOFs: Zinc metal-organic frameworks with pendant aldehyde and methoxy groups are prepared. The aldehyde-tagged MOF takes up 2,4-dinitrophenylhydrazine, reacting to form a hydrazone-functionalized MOF which is crystallographically characterized. Use of both aldehyde- and methoxy-functionalized dicarboxylates leads to MOFs containing both ligands, of which the aldehyde groups can be selectively reacted. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：8482 / 8486
页数：5
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