Hydrolytic polycondensation of ethyl silicate with copper salts of mineral and organic acids in sol-gel process

被引:1
|
作者
Sviderskii, VA [1 ]
Voronkov, MG
Klimenko, SV
Bystrov, DN
机构
[1] Ukrainian Natl Tech Univ, Kiev Polytech Inst, Kiev, Ukraine
[2] Russian Acad Sci, Siberian Div, Favorskii Inst Chem, Irkutsk 664003, Russia
关键词
Copper - Polycondensation - Salts - Silicates - Sol-gel process;
D O I
10.1023/A:1015559210585
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The structure and composition of polyheterosiloxanes formed in hydrolytic polycondensation of ethyl silicate in the presence of copper salts under the conditions of base catalysis (NH4OH) were studied as influenced by the nature of acid anion (SO42-, Cl-, NO3-, CH3COO-).
引用
收藏
页码:2087 / 2090
页数:4
相关论文
共 50 条
  • [22] Phase selective synthesis of copper sulfides by non-hydrolytic sol-gel methods
    Zhou, Xiuquan
    Soldat, Anne Christine
    Lind, Cora
    RSC ADVANCES, 2014, 4 (02): : 717 - 726
  • [23] PREPARATION OF INORGANIC ORGANIC HYBRID GELS BY THE SOL-GEL PROCESS
    KOHJIYA, S
    OCHIAI, K
    YAMASHITA, S
    JOURNAL OF NON-CRYSTALLINE SOLIDS, 1990, 119 (02) : 132 - 135
  • [24] Ultrafiltration Carbon Membranes from Organic Sol-Gel Process
    Qin, Guotong
    He, Jinling
    Wei, Wei
    CHEMICAL ENGINEERING COMMUNICATIONS, 2016, 203 (03) : 381 - 388
  • [25] INORGANIC-ORGANIC HYBRID MATERIALS BY THE SOL-GEL PROCESS
    JOARDAR, S
    JONES, MA
    WARD, TC
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 137 - PMSE
  • [26] Organic inorganic hybrid materials by the sol-gel process - Introduction
    Klein, LC
    Sanchez, C
    JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 1995, 5 (02) : U4 - U4
  • [27] Cathodoluminescence studies of yttrium silicate:cerium phosphors synthesised by a sol-gel process
    Marsh, PJ
    Silver, J
    Vecht, A
    Newport, A
    JOURNAL OF LUMINESCENCE, 2002, 97 (3-4) : 229 - 236
  • [28] Ion transport changes in the early stages of the sol-gel process in the silicate system
    Wasiucionek, M
    VII NATIONAL SYMPOSIUM ON FAST ION CONDUCTORS, 2000, 27 : 122 - 125
  • [29] Initial Steps of the Sol-Gel Process: Modeling Silicate Condensation in Basic Medium
    Henschel, Henning
    Schneider, Andreas M.
    Prosenc, Marc H.
    CHEMISTRY OF MATERIALS, 2010, 22 (17) : 5105 - 5111
  • [30] Study on strontium doped tricalcium silicate synthesized through sol-gel process
    Liu, Wai-Ching
    Hu, Chih-Chien
    Tseng, Yuan-Yun
    Sakthivel, Rajalakshmi
    Fan, Kuei-Sheng
    Wang, An-Ni
    Wang, Yi-Min
    Chung, Ren-Jei
    MATERIALS SCIENCE AND ENGINEERING C-MATERIALS FOR BIOLOGICAL APPLICATIONS, 2020, 108 (108):