Synthesis and Capacitance Characteristics of the Graphene Grafted Polypyrrole Composites

被引:3
|
作者
Liu Jian-Hua [1 ]
Zhang Shi-Lu [1 ]
Yu Mei [1 ]
An Jun-Wei [1 ]
Li Song-Mei [1 ]
机构
[1] Beihang Univ, Sch Mat Sci & Engn, Beijing 100191, Peoples R China
基金
中国国家自然科学基金;
关键词
graphene; polypyrrole; in-situ synthesis; composites; specific capacitance; FABRICATION;
D O I
10.3724/SP.J.1077.2013.12289
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The graphene grafted polypyrrole composites were in situ synthesized with the chemical grafting method. The testing and characterization of the structure and morphology indicated that the pyrrole monomer in the composites was grafted with the graphene lamellar layer on-chip evenly distributed through the amide bond, and a large number of the pyrrole grow into a chain connecting to the graphene layers. The synergistic effect of graphene and polypyrrole made the conductivity of the composites significantly improve from 0.22 S/cm to 3.32 S/cm. The capacitance value of graphene grafted polypyrrole composites reached 284 F/g, which increased by 52% compared with the specific capacitance of pure polypyrrole 186 F/g. It indicated the composites's excellent characteristics of the capacitor.
引用
收藏
页码:403 / 408
页数:6
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