Selective hydrogenation of α,β-unsaturated aldehydes over Pt supported on cerium-zirconium mixed oxide of different composition

被引：3

作者：

Vikanova, Kseniia V. ^{[1
]}

Redina, Elena A. ^{[1
]}

Kapustin, Gennady I. ^{[1
]}

Mishin, Igor V. ^{[1
]}

Davshan, Nikolay A. ^{[1
]}

Kustov, Leonid M. ^{[1
,2
,3
]}

机构：

[1] Russian Acad Sci, ND Zelinsky Inst Organ Chem, Moscow 119991, Russia

[2] Natl Univ Sci & Technol MISiS, Moscow 119049, Russia

[3] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia

来源：

MENDELEEV COMMUNICATIONS | 2022年 / 32卷 / 04期

基金：

俄罗斯科学基金会;

关键词：

cinnamaldehyde; cinnamyl alcohol; cerium oxide; zirconium oxide; selective hydrogenation; unsaturated alcohol synthesis; platinum; alpha; beta-unsaturated aldehydes; MECHANICAL-PROPERTIES; CATALYTIC-PROPERTIES; CARBONYL-COMPOUNDS; CINNAMALDEHYDE; SURFACE; NANOPARTICLES; ALCOHOL;

D O I：

10.1016/j.mencom.2022.07.019

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cerium-zirconium mixed oxides with different Ce/Zr ratio were prepared and used as supports for Pt-containing catalysts. The study of the catalysts in the cinnamaldehyde hydrogenation reaction has shown that cinnamaldehyde conversion and cinnamyl alcohol selectivity strongly depend on the CeO2 content in the support. The highest cinnamyl alcohol yield of 81% was obtained in 105 min at room temperature and atmospheric pressure over the 1%Pt/CeO2-ZrO2 catalyst with Ce : Zr atomic ratio equal to 4 : 1.

引用

页码：488 / 491

页数：4

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