Methane oxidative coupling in an undiluted reaction mixture in a reactor-adsorber system with gas recirculation

被引：12
|
作者：
Machocki, A
机构：
[1] Maria Curie-Skłodowska Univ., Faculty of Chemistry, Department of Chemical Technology, 20031 Lublin
来源：
APPLIED CATALYSIS A-GENERAL | 1996年 / 146卷 / 02期
关键词：
methane conversion; methane oxidative coupling; methane oxidative dimerization; reaction mixture without diluent; reaction products adsorption; gas recirculation; ethylene production;
D O I：
10.1016/S0926-860X(96)00178-0
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Results of the oxidative coupling of methane obtained in a reactor-adsorber system with gas recirculation, with a continuous supply of the methane-oxygen reaction mixture without a diluent gas (p(CH4 + O-2) = 1 atm, CH4:O-2 = 20:1), are described. At total methane conversion equal to 94%, the O-2, hydrocarbon selectivity of the process was 70%, while ethylene contents was 92% in the obtained hydrocarbons.
引用
收藏
页码：391 / 400
页数：10
相关论文
共 50 条
  • [21] Methane Oxidative Coupling: Synthesis of Membrane Reactor Networks
    Godini, H. R.
    Jaso, S.
    Xiao, Shengnan
    Arellano-Garcia, H.
    Omidkhah, M.
    Wozny, G.
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (22) : 7747 - 7761
  • [22] Recognition of Oxidative Coupling of Methane Reactor Performance Patterns
    Kim, Mijin
    Repke, Jens-Uwe
    Schomaecker, Reinhard
    Khodadadi, Abbas Ali
    Wozny, Guenter
    Goerke, Oliver
    Godini, Hamid Reza
    CHEMICAL ENGINEERING & TECHNOLOGY, 2022, 45 (04) : 694 - 708
  • [23] Oxidative coupling of methane in a solid oxide membrane reactor
    Guo, XM
    Hidajat, K
    Ching, CB
    Chen, HF
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1997, 36 (09) : 3576 - 3582
  • [24] Oxidative coupling of methane to ethylene: Development of membrane reactor
    Zein, SHS
    Mohamed, AR
    Zabidi, NAM
    Bhatia, S
    ADVANCES IN MALAYSIAN ENERGY RESEARCH 2000, 2001, : 317 - 328
  • [25] STUDIES ON THE CERAMIC MEMBRANE REACTOR FOR OXIDATIVE COUPLING OF METHANE
    HE Ren-Jin(Department of Chemistry Jinan University Guangzhou
    Journal of Natural Gas Chemistry, 1996, (04) : 306 - 319
  • [26] SIMULATION OF A CATALYTIC MEMBRANE REACTOR FOR OXIDATIVE COUPLING OF METHANE
    CHENG, S
    SHUAI, X
    AICHE JOURNAL, 1995, 41 (06) : 1598 - 1601
  • [27] Oxidative coupling of methane in a modified γ-alumina membrane reactor
    Lu, YP
    Dixon, AG
    Moser, WR
    Ma, YH
    CHEMICAL ENGINEERING SCIENCE, 2000, 55 (21) : 4901 - 4912
  • [28] EFFECT OF PRESSURE ON THE OXIDATIVE COUPLING REACTION OF METHANE
    EKSTROM, A
    REGTOP, R
    BHARGAVA, S
    APPLIED CATALYSIS, 1990, 62 (02): : 253 - 269
  • [29] Simulation and Experimental Studies of Methane Oxidative Coupling Reaction in a Bench Scale Fixed Bed Reactor
    Valadkhani, A.
    Shahrokhi, M.
    Pishvaie, M. R.
    Zarrinpashneh, S.
    ENERGY SOURCES PART A-RECOVERY UTILIZATION AND ENVIRONMENTAL EFFECTS, 2013, 35 (15) : 1418 - 1426
  • [30] REACTION MODELING OF THE CATALYTIC OXIDATIVE COUPLING OF METHANE
    KOLTS, JH
    KIMBLE, JB
    ROHLFING, DC
    DAHL, IM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1988, 196 : 258 - COLL
12345