Synthesis and electroluminescent properties of polyazomethine-type conjugated polymers containing heterocyclic phenothiazine and carbazole moiety

被引：8
|
作者：
Jeong, JW [1 ]
Kwon, Y
Baek, JJ
Park, LS
Lee, EW
Han, YS
Kim, HT
机构：
[1] Daegu Univ, Dept Chem Engn, Res Inst Nano Technol, Gyeongbuk 712714, South Korea
[2] Kyungpook Natl Univ, Dept Polymer Sci, Taegu 702701, South Korea
[3] Kyungpook Natl Univ, Dept Phys, Taegu 702701, South Korea
[4] Kyungpook Natl Univ, Adv Display Mfg Res Ctr, Taegu 702701, South Korea
来源：
JOURNAL OF NONLINEAR OPTICAL PHYSICS & MATERIALS | 2005年 / 14卷 / 04期
关键词：
light emitting diode (LED); heterocyclic conjugated copolymer; azomethine unit; phenothiazine; carbazole;
D O I：
10.1142/S0218863505003006
中图分类号：
O43 [光学];
学科分类号：
070207 ; 0803 ;
摘要：
Polyazomethine-type conjugated polymers were synthesized by Schiff-base reaction. One was poly(PZ-PBI) with alternating phenothiazine (PZ) and azomethine units (-C = N-), and the other was poly(CZ-PBI) comprising alternating carbazole (CZ) and azomethine groups. Conjugated polymers exhibited improved solubility in common organic solvents due to alkyl side chains on phenothiazine and carbazole rings as well as polar azomethine groups in main chains. Single- and double-layer PLEDs were fabricated. Their electroluminescent properties were studied from the viewpoint of polymer structure vs. emission color and efficiency.
引用
收藏
页码：545 / 553
页数：9
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