Origin of single molecule magnet behavior of a trinuclear [Ni2Dy] cluster

被引：4
|
作者：
Klokishner, Sophia [1 ]
Reu, Oleg [1 ]
机构：
[1] Moldavian Acad Sci, Inst Appl Phys, MD-2028 Kishinev, Moldova
来源：
CHEMICAL PHYSICS LETTERS | 2012年 / 552卷
关键词：
CYANO-BRIDGED CLUSTERS; MAGNETIZATION; SPIN; ANISOTROPY; COMPLEXES; MN(III); BARRIER; DY; CRYSTAL;
D O I：
10.1016/j.cplett.2012.09.065
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The manifestations of single ion anisotropy of the Dy-III ion in the key physical properties of the [L2Ni2Dy][ClO4] single molecule magnet have been examined. The crystal field acting on the Dy-III ion and the exchange interaction coupling the Dy-III and Ni-II ions are included in the model. It is shown that the role of the Ni-II ions is only to increase the total angular momentum of the cluster via coupling through superexchange with the Dy-III ion. The model describes well the observed temperature dependence of the magnetic susceptibility and the field dependence of magnetization. (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码：130 / 135
页数：6
相关论文
共 50 条
  • [21] Pentanuclear dysprosium hydroxy cluster showing single-molecule-magnet behavior
    Gamer, Michael T.
    Lan, Yanhua
    Roesky, Peter W.
    Powell, Annie K.
    Clerac, Rodolphe
    INORGANIC CHEMISTRY, 2008, 47 (15) : 6581 - 6583
  • [22] Calixarene-supported hexadysprosium cluster showing single molecule magnet behavior
    Bi YanFeng
    Xu GuanCheng
    Liao WuPing
    Du ShangChao
    Deng RuiPing
    Wang BingWu
    SCIENCE CHINA-CHEMISTRY, 2012, 55 (06) : 967 - 972
  • [23] Unprecedented Octanuclear DyIII Cluster Exhibiting Single-Molecule Magnet Behavior
    Lacelle, Thomas
    Brunet, Gabriel
    Holmberg, Rebecca J.
    Gabidullin, Bulat
    Mumgesu, Muralee
    CRYSTAL GROWTH & DESIGN, 2017, 17 (10) : 5044 - 5048
  • [24] Single molecule magnet behaviour in a {Dy4P2} octahedron
    Zangana, Karzan H.
    Pineda, Eufemio Moreno
    Winpenny, Richard E. P.
    DALTON TRANSACTIONS, 2015, 44 (28) : 12522 - 12525
  • [25] Magnetic and 57Fe Mossbauer Study of the Single Molecule Magnet Behavior of a Dy3Fe7 Coordination Cluster
    Abbas, Ghulam
    Lan, Yanhua
    Mereacre, Valeriu
    Wernsdorfer, Wolfgang
    Clerac, Rodolphe
    Buth, Gernot
    Sougrati, Moulay T.
    Grandjean, Fernande
    Long, Gary J.
    Anson, Christopher E.
    Powell, Annie K.
    INORGANIC CHEMISTRY, 2009, 48 (19) : 9345 - 9355
  • [26] Hard Single-Molecule Magnet Behavior by a Linear Trinuclear Lanthanide-[1]Metallocenophane Complex
    Latendresse, Trevor P.
    Bhuvanesh, Nattamai S.
    Nippe, Michael
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (42) : 14877 - 14880
  • [27] Chiral and kryptoracemic Dy(iii) complexes with field-induced single molecule magnet behavior
    Zhang, Ying-Ying
    Yu, Jing-Tao
    Li, Bo
    Li, De-Jing
    Gu, Zhi-Gang
    Sun, Xiao-Fan
    Cai, Hong-Ling
    Kostakis, George E.
    Peng, Guo
    CRYSTENGCOMM, 2018, 20 (32): : 4582 - 4589
  • [28] Manipulating On/Off Single-Molecule Magnet Behavior in a Dy(III)-Based Photochromic Complex
    Ma, Yu-Juan
    Hu, Ji-Xiang
    Han, Song-De
    Pan, Jie
    Li, Jin-Hua
    Wang, Guo-Ming
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (05) : 2682 - 2689
  • [29] Heterometallic hexanuclear Ni4M2 (M = Dy, Y) complexes: structure and single-molecule magnet for the Dy(III) derivative
    Pei, Shaomin
    Hu, Zhaobo
    Chen, Zilu
    Yu, Shui
    Li, Bo
    Liang, Yuning
    Liu, Dongcheng
    Yao, Di
    Liang, Fupei
    DALTON TRANSACTIONS, 2018, 47 (06) : 1801 - 1807
  • [30] A Trinuclear Radical-Bridged Lanthanide Single-Molecule Magnet
    Gould, Colin A.
    Darago, Lucy E.
    Gonzalez, Miguel I.
    Demir, Selvan
    Long, Jeffrey R.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (34) : 10103 - 10107
12345