Baeyer-Villiger oxidation with potassium peroxomonosulfate supported on acidic silica gel

被引：38
|
作者：
González-Nuñez, ME [1 ]
Mello, R [1 ]
Olmos, A [1 ]
Asensio, G [1 ]
机构：
[1] Univ Valencia, Dept Quim Organ, E-46100 Burjassot, Valencia, Spain
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2005年 / 70卷 / 26期
关键词：
D O I：
10.1021/jo051614v
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Potassium peroxomonosulfate deposited onto silica (SiO2KHSO5)-K-. efficiently reacts with ketones in dichloromethane at room temperature to give the corresponding esters or lactones in quantitative yields. This method avoids hydrolysis of the reaction products. The Baeyer-Villiger reaction is catalyzed by potassium hydrogensulfate present in the supported reagent.
引用
收藏
页码：10879 / 10882
页数：4
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