Synthesis and Solid-state Structures of 1,3-and 1,4-Bis(diethylgallyl)benzene

被引：0
|
作者：
Izundu, Joseph [1 ]
Jutzi, Peter [1 ]
Neumann, Beate [1 ]
Sielemann, Henning [1 ]
Stammler, Hans-Georg [1 ]
机构：
[1] Univ Bielefeld, Dept Chem, D-33501 Bielefeld, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2009年 / 64卷 / 11-12期
关键词：
Bis(diethylgallyl)benzenes; Diethylgallyl Bridging Units; Dialkyl(aryl)gallium Compounds; Organogallium(III) Compounds; MOLECULAR-STRUCTURES; CRYSTAL-STRUCTURES; ARYLSTANNANES; GALLIUM;
D O I：
10.1515/znb-2009-11-1218
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The compounds 1,3-bis(diethylgallyl)benzene (3) and 1,4- bis(diethylgallyl)benzene (6) were prepared by reaction of the corresponding chloromercuriobenzenes with an excess of triethylgallium by applying pressure and higher temperatures. These compounds very easily undergo redistribution reactions in solution and in the solid state. Extremely air-sensitive crystals suitable for an X-ray crystal structure analysis were obtained from triethylgallium as solvent. The structural studies revealed the presence of tetra-coordinated carbon and gallium atoms in symmetric aryl-diethylgallyl bridging units. The coordination behavior of 3 and 6 in the solid state is quite different from that of the corresponding methyl-substituted compounds.
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收藏
页码：1375 / 1380
页数：6
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