A trans-platinum(II) complex as a single-molecule insulator

被引：0
|
作者：
Mayor, M [1 ]
von Hänisch, C [1 ]
Weber, HB [1 ]
Reichert, J [1 ]
Beckmann, D [1 ]
机构：
[1] Forschungszentrum Karlsruhe GmbH, Inst Nanotechnol, D-76021 Karlsruhe, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 07期
关键词：
electron transport; insulators; molecular electronics; platinum; single-molecule studies;
D O I：
10.1002/1521-3773(20020402)41:7<1183::AID-ANIE1183>3.0.CO;2-Z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A further component for molecular electronics: A single molecule insulator is realized by immobilizing a platinum(II) complex between two gold electrodes (see picture). The current/voltage characteristics of the setup shows the typical behavior of an insulator with a tunnel barrier height of 2.5 eV.
引用
收藏
页码：1183 / +
页数：5
相关论文
共 50 条
  • [11] Synthesis, characterization and biological activity of trans-platinum(II) complexes with chloroquine
    Navarro, Maribel
    Castro, William
    Higuera-Padilla, Angel R.
    Sierraalta, Anibal
    Jesus Abad, Maria
    Taylor, Peter
    Sanchez-Delgado, Roberto A.
    JOURNAL OF INORGANIC BIOCHEMISTRY, 2011, 105 (12) : 1684 - 1691
  • [12] Trans-Platinum Complexes in Cancer Therapy
    Coluccia, Mauro
    Natile, Giovanni
    ANTI-CANCER AGENTS IN MEDICINAL CHEMISTRY, 2007, 7 (01) : 111 - 123
  • [13] RADIOTOXICITY OF PLATINUM-195M-LABELED TRANS-PLATINUM(II) IN MAMMALIAN-CELLS
    HOWELL, RW
    KASSIS, AI
    ADELSTEIN, SJ
    RAO, DV
    WRIGHT, HA
    HAMM, RN
    TURNER, JE
    SASTRY, KSR
    RADIATION RESEARCH, 1994, 140 (01) : 55 - 62
  • [14] A kinetic investigation of mononuclear trans-platinum(II) complexes with mixed amine ligands
    Olusegun, Moses Ariyo
    Reddy, Desigan
    Jaganyi, Deogratius
    TRANSITION METAL CHEMISTRY, 2020, 45 (05) : 295 - 301
  • [15] INTERACTIONS OF CIS-PLATINUM(II) AND TRANS-PLATINUM(II) COMPLEXES WITH DEHYDROGENASE ENZYMES IN PRESENCE OF DIFFERENT MONO-NUCLEOTIDES AND POLYNUCLEOTIDES - EVIDENCE FOR A TERNARY COMPLEX
    FRIEDMAN, ME
    MELIUS, P
    TEGGINS, JE
    MCAULIFFE, CA
    BIOINORGANIC CHEMISTRY, 1978, 8 (04): : 341 - 353
  • [16] Towards Antitumor Active trans-Platinum Compounds
    Aris, Sheena M.
    Farrell, Nicholas P.
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (10) : 1293 - 1302
  • [17] A New Single-Molecule Magnet Based on a Cage Cobalt(II) Complex
    Aleshin, D. Yu.
    Pavlov, A. A.
    Belova, S. A.
    Efimov, N. N.
    Belov, A. S.
    Novikov, V. V.
    Voloshin, Ya. Z.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 64 (12) : 1532 - 1537
  • [18] Single-Molecule Dynamics of the Human RNA Polymerase II Preinitiation Complex
    Cunnison, Rory
    Gonchar, Oksana
    Grimm, Jonathan
    Lavis, Luke
    Zhang, Zhengjian
    Revyakin, Andrey G.
    BIOPHYSICAL JOURNAL, 2020, 118 (03) : 188A - 188A
  • [19] A New Single-Molecule Magnet Based on a Cage Cobalt(II) Complex
    D. Yu. Aleshin
    A. A. Pavlov
    S. A. Belova
    N. N. Efimov
    A. S. Belov
    V. V. Novikov
    Ya. Z. Voloshin
    Russian Journal of Inorganic Chemistry, 2019, 64 : 1532 - 1537
  • [20] A Computational Approach for Hydrolysis of the Third-Generation Anticancer Drug: Trans-Platinum(Ii) Complex of 3-Aminoflavone
    Sadeghi, N.
    Ghiasi, R.
    Jamehbozorgi, S.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2018, 59 (08) : 1791 - 1796
12345