Flower-like NiCo2O4 Microstructures as Promising Anode Material for High Performance Lithium-Ion Batteries: Facile Synthesis and its Lithium Storage Properties

被引:14
|
作者
Sun, Yuanwei [1 ]
Zuo, Xintao [1 ]
Xu, Dan [1 ]
Sun, Dezhi [1 ]
Zhang, Xianxi [1 ]
Zeng, Suyuan [1 ]
机构
[1] Liaocheng Univ, Sch Chem & Chem Engn, Shandong Prov Key Lab Chem Energy Storage & Novel, Liaocheng 252059, Peoples R China
来源
CHEMISTRYSELECT | 2016年 / 1卷 / 16期
基金
中国国家自然科学基金;
关键词
anode material; flower-like; lithium ion battery; NiCo2O4 simple method; ENHANCED ELECTROCHEMICAL PERFORMANCE; HOLLOW SPHERES; CAPACITY; MNCO2O4; NANOPARTICLES; MICROSPHERES; ELECTRODE; ZNCO2O4; NANOCOMPOSITES; CYCLABILITY;
D O I
10.1002/slct.201601147
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Flower-like NiCo2O4 microstructures were prepared through thermal decomposition of the Ni-Co- intermediate. The as-prepared NiCo2O4 microstructures are proved to be mesoporous according to the N-2 adsorption-desorption experiments, which is beneficial for the improvement of the electrochemical performance. The as-prepared NiCo2O4 microstructures exhibit excellent cycling stability (1128 mA h g(-1) at a current density of 1000 mA g(-1), after 330 cycles) when being used as the anode materials for lithium-ion batteries (LIBs). Even being discharged a high current density of 5000 mA g(-1), the discharge capacity can still reach 948.1 mA h g(-1). The superior electrochemical properties can be attributed to the unique 3D structure, structural stability and porous structure, all of which can effectively increase the contact area of the electrode-electrolyte and improve the stability of anode.
引用
收藏
页码:5129 / 5136
页数:8
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