Control of molecular weight in Ni(II)-catalyzed polymerization via the reaction medium

被引：63
|
作者：
Guironnet, Damien [1 ]
Ruenzi, Thomas [1 ]
Goettker-Schnetmann, Inigo [1 ]
Mecking, Stefan [1 ]
机构：
[1] Univ Konstanz, Dept Chem, Chair Chem Mat Sci, D-78464 Constance, Germany
来源：
CHEMICAL COMMUNICATIONS | 2008年 / 40期
关键词：
D O I：
10.1039/b811888d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction medium controls polymerization with highly active (kappa(2)-P,O)-phosphinesulfonato nickel methyl complexes to afford polyethylenes ranging from low molecular weight (M-n) branched material to high molecular weight (M-n) strictly linear polymer.
引用
收藏
页码：4965 / 4967
页数：3
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