Microstructure and microwave dielectric properties of Bi12SiO20 ceramics
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作者:
Jeong, Byoung-Jik
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Korea Univ, Dept Mat Sci & Engn, Seoul 136701, South KoreaKorea Univ, Dept Mat Sci & Engn, Seoul 136701, South Korea
Jeong, Byoung-Jik
[1
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Joung, Mi-Ri
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Korea Univ, Dept Mat Sci & Engn, Seoul 136701, South KoreaKorea Univ, Dept Mat Sci & Engn, Seoul 136701, South Korea
Joung, Mi-Ri
[1
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Kweon, Sang-Hyo
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Korea Univ, Dept Mat Sci & Engn, Seoul 136701, South KoreaKorea Univ, Dept Mat Sci & Engn, Seoul 136701, South Korea
Kweon, Sang-Hyo
[1
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Kim, Jin-Seong
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Korea Univ, Dept Mat Sci & Engn, Seoul 136701, South KoreaKorea Univ, Dept Mat Sci & Engn, Seoul 136701, South Korea
Kim, Jin-Seong
[1
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Nahm, Sahn
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Korea Univ, Dept Mat Sci & Engn, Seoul 136701, South KoreaKorea Univ, Dept Mat Sci & Engn, Seoul 136701, South Korea
Nahm, Sahn
[1
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Choi, Ji-Won
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KIST, Ctr Elect Mat, Seoul 137791, South KoreaKorea Univ, Dept Mat Sci & Engn, Seoul 136701, South Korea
Choi, Ji-Won
[2
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Hwang, Seong-Ju
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Ewha Womans Univ, Dept Chem & Nano Sci, Ctr Intelligent Nanobio Mat, Seoul 120750, South KoreaKorea Univ, Dept Mat Sci & Engn, Seoul 136701, South Korea
Hwang, Seong-Ju
[3
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机构:
[1] Korea Univ, Dept Mat Sci & Engn, Seoul 136701, South Korea
[2] KIST, Ctr Elect Mat, Seoul 137791, South Korea
[3] Ewha Womans Univ, Dept Chem & Nano Sci, Ctr Intelligent Nanobio Mat, Seoul 120750, South Korea
Bi12SiO20 ceramics were well sintered at 800 degrees C after calcination at 700 degrees C. A liquid phase of composition Bi2O3 was formed during the sintering at temperatures >= 800 degrees C and assisted the densification of the Bi12SiO20 ceramics. When the sintering temperature exceeded 800 degrees C, however, the relative density, epsilon(r), and Q x f values of the Bi12SiO20 ceramics decreased, probably due to the formation of a large amount of the liquid phase. The Bi12SiO20 ceramics sintered at 800 degrees C for 5.0 h exhibited excellent microwave dielectric properties with a high epsilon(r) of 43, a high Q x f of 86,802 GHz and a small tau(f) of -10.39 ppm/degrees C. (C) 2012 Elsevier Ltd. All rights reserved.