Picture of a chelate in exchange: the crystal structure of NaHoDOTMA, a 'semi'-hydrated chelate

被引：6

作者：

Payne, Katherine M. ^{[1
]}

Valente, Edward J. ^{[2
]}

Aime, Silvio ^{[3
,4
]}

Botta, Mauro ^{[5
]}

Woods, Mark ^{[1
,6
]}

机构：

[1] Portland State Univ, Dept Chem, Portland, OR 97201 USA

[2] Univ Portland, Dept Chem, Portland, OR 97203 USA

[3] Univ Turin, Dept Chem IFM, I-10125 Turin, Italy

[4] Univ Turin, Mol Imaging Ctr, I-10125 Turin, Italy

[5] Univ Piemonte Orientale Amedeo Avogadro, Dipartimento Sci Innovaz Tecnol, I-15121 Alessandria, Italy

[6] Oregon Hlth & Sci Univ, Adv Imaging Res Ctr, Portland, OR 97239 USA

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 23期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

LANTHANIDE(III) COMPLEXES; DOTA COMPLEXES; DYNAMICS; EUROPIUM;

D O I：

10.1039/c3cc38814j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crystallography generally only provides static structural information. This can render it an ineffective technique for probing dynamic solution state processes. A crystal of HoDOTMA affords unique structures that effectively represent that of a lanthanide tetra-acetate chelate mid-way through the water exchange process.

引用

页码：2320 / 2322

页数：3

共 50 条

[31] LINE DRAWINGS OF CHELATE STRUCTURE MODELS
SMITH, RL
CHEMISTRY & INDUSTRY, 1956, (17) : 333 - 333
[32] EXCHANGE OF RARE-EARTH IONS IN CHELATE SOLUTIONS
BHAUMIK, ML
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1965, 27 (01): : 243 - &
[33] OXINE BASED CHELATE EXCHANGE RESINS .I.
BERNHARD, H
GRASS, F
MONATSHEFTE FUR CHEMIE, 1967, 98 (03): : 1050 - &
[34] SUBSTITUTION KINETICS OF CHELATE COMPLEXES AS STUDIED BY ISOTOPIC EXCHANGE
ELIAS, H
JOURNAL OF RADIOANALYTICAL CHEMISTRY, 1976, 30 (01): : 25 - 34
[35] CRYSTAL STRUCTURE OF COPPER(2) CHELATE OF N,N'-ETHYLENEBIS(L-EPHEDRINE)
MOTOHASHI, M
AMANO, Y
UNO, T
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1968, 41 (09) : 2007 - +
[36] PAMAM Dendrimers Conjugated with an Uncharged Gadolinium(III) Chelate with a Fast Water Exchange: The Influence of Chelate Charge on Rotational Dynamics
Polasek, Miloslav
Hermann, Petr
Peters, Joop A.
Geraldes, Carlos F. G. C.
Lukes, Ivan
BIOCONJUGATE CHEMISTRY, 2009, 20 (11) : 2142 - 2153
[37] PREPARATION, ISOLATION AND IDENTIFICATION OF BLEOMYCIN CO-57 CHELATE WITH SPECIAL REFERENCE TO ITS CHELATE STRUCTURE
KAKINUMA, J
ORII, H
JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS, 1979, 16 (01): : 200 - 200
[38] GROWTH AND CRYSTAL SYMMETRY OF METAL CHELATE SALT CRYSTALS
VANUITERT, LG
TREUTING, RG
JOURNAL OF CHEMICAL PHYSICS, 1960, 32 (02): : 322 - 324
[39] A CHELATE RING STRUCTURE OF A PLATINUM(II) DIBORATE
MIYAMOTO, T
ICHIDA, H
CHEMISTRY LETTERS, 1991, (03) : 435 - 436
[40] STRUCTURE OF THIOPICOLINEANILIDES AND THEIR CHELATE COMPLEXES .I.
GLAZNEVA, GV
MAMAEVA, EK
ZEIF, AP
JOURNAL OF GENERAL CHEMISTRY USSR, 1966, 36 (08): : 1503 - &

← 1 2 3 4 5 →