Copper-Containing Catalysts for the Oxidative Dehydrogenation of Organic Compounds

被引：8

作者：

Krasnobaeva, O. N. ^{[1
]}

Belomestnykh, I. P. ^{[2
]}

Nosova, T. A. ^{[1
]}

Elizarova, T. A. ^{[1
]}

Isagulyants, G. V. ^{[2
]}

Danilov, V. P. ^{[1
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

[2] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2012年 / 57卷 / 12期

关键词：

OXIDE CATALYSTS; HYDROXO SALTS; MAGNESIUM; ALUMINUM; ALCOHOLS; HYDROCARBONS; OXYDEHYDROGENATION; TUNGSTEN; ALKANES; NICKEL;

D O I：

10.1134/S003602361212011X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A method of doping magnesium aluminum hydrotalcites, which are precursors for oxidative dehydrogenation oxide catalysts of various compositions, with copper(II) was developed, and copper(II)-containing oxide catalyst samples were synthesized. The catalytic properties of these catalysts were studied in the oxidative dehydrogenation of ethane, propane, and hexane. The conversion of ethane into ethylene on the copper-containing catalysts was established to proceed with high selectivities (90-97%) and at low temperatures (400-450 degrees C).

引用

页码：1540 / 1544

页数：5

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