Highly Sensitive and Selective Chemosensor for Cu2+ Based on a Schiff Base

被引：11

作者：

Cao Ben-nan ^{[1
]}

Hu Qin ^{[1
]}

Huang Yan ^{[2
]}

Jia Chun-man ^{[1
]}

Zhang Qi ^{[1
,2
]}

机构：

[1] Hainan Univ, Hainan Prov Key Lab Fine Chem, Key Study Ctr, Minist Educ Trop Resources Utilizat, Haikou 570228, Peoples R China

[2] Jiangsu Univ, Dept Chem & Chem Engn, Zhenjiang 212013, Jiangsu, Peoples R China

来源：

CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2013年 / 29卷 / 03期

基金：

中国国家自然科学基金;

关键词：

Chemosensor; Schiff base; Copper ion; Naked-eye detection; Quench; FLUORESCENT SENSORS; ELECTRON-TRANSFER; LIVING CELLS; RHODAMINE; COORDINATION; DERIVATIVES; COPPER(II); DESIGN; PROBE; ZN2+;

D O I：

10.1007/s40242-013-2449-4

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new chemosensor based on a Schiff base has been designed and synthesized. Its sensing behavior toward various metal ions was investigated by fluorescence and UV-Vis spectroscopic methods. The fluorescence of the sensor was quenched and the color rapidly changed from canary yellow to brown after the addition of Cu2+, while no changes occurred after the addition of other metal ions, which contributes to the detection of Cu2+ with naked eyes. The fluorescence quantum yield of the ligand was calculated to be 0.52. The corresponding detection limit of Cu2+ was 5.721x10(-7)mol/L, and the 1:1 binding mode of the sensor with Cu2+ was revealed by Job's plot.

引用

下载

页码：419 / 423

页数：5

共 50 条

[41] Synthesis, characterization and applications of schiff base chemosensor for determination of Cu2+ ions
Khan, Sikandar
Muhammad, Mian
Al-Saidi, Hamed M.
Hassanian, Athar Abdulfattah
Alharbi, Walaa
Alharbi, Khadijah H.
JOURNAL OF SAUDI CHEMICAL SOCIETY, 2022, 26 (04)
[42] Preparation and Application of a Fast, Naked-Eye, Highly Selective, and Highly Sensitive Fluorescent Probe of Schiff Base for Detection of Cu2+
Liu, Juan
Cheng, Peng-Yu
Chen, Sai
Wang, Meng
Wei, Kai
Li, Yuan
Cao, Yao-Yao
Wang, Xing
Li, Hong-Lei
CHEMOSENSORS, 2023, 11 (11)
[43] A highly selective and sensitive chemosensor for L-tryptophan by employing a Schiff based Cu(II) complex
Saini, Anoop Kumar
Saraf, Mohit
Kumari, Pratibha
Mobin, Shaikh M.
NEW JOURNAL OF CHEMISTRY, 2018, 42 (05) : 3509 - 3518
[44] A new carbazole-based Schiff-base as fluorescent chemosensor for selective detection of Fe3+ and Cu2+
Yang, Lianlian
Zhu, Weiju
Fang, Min
Zhang, Qing
Li, Cun
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 109 : 186 - 192
[45] A simple turn-off fluorescent chemosensor based on a Schiff base structure for ultrafast and highly selective trace detection of Cu2+ ions in aqueous solutions
Wang, Jing
Ren, Lu
Sun, Qiang
Liu, Yanqi
Jia, Wanru
Zhang, Huihong
Zhang, Dawei
Analytical Methods, 2024, 16 (46) : 7864 - 7872
[46] A novel imidazole-derived Schiff base as selective and sensitive colorimetric chemosensor for fluorescent detection of Cu2+ in methanol with mixed aqueous medium
Slassi, Siham
Aarjane, Mohammed
Amine, Amina
APPLIED ORGANOMETALLIC CHEMISTRY, 2021, 35 (11)
[47] A selective Fluorescence Chemosensor: Pyrene motif Schiff base derivative for detection of Cu2+ ions in living cells
Saravanan, Arjunan
Subashini, Gopalan
Shyamsivappan, Selvaraj
Suresh, Thangaraj
Kadirvelu, Krishna
Bhuvanesh, Nanjan
Nandhakumar, Raju
Mohan, Palathurai Subramaniam
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2018, 364 : 424 - 432
[48] Di-Triphenylamine-based AIE active Schiff base for highly sensitive and selective fluorescence sensing of Cu2+ and Fe3+
Barot, Yash B.
Anand, Vivek
Mishra, Roli
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2022, 426
[49] A highly sensitive, selective, colorimetric and near-infrared fluorescent turn-on chemosensor for Cu2+ based on BODIPY
Yin, Shouchun
Leen, Volker
Van Snick, Sven
Boens, Noel
Dehaen, Wim
CHEMICAL COMMUNICATIONS, 2010, 46 (34) : 6329 - 6331
[50] Sensing of Cyanide Using Highly Selective Thiazole-based Cu2+ Chemosensor
Helal, Aasif
Kim, Sebeom
Kim, Hong-Seok
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2011, 32 (08): : 3123 - 3126

← 1 2 3 4 5 →