Isentropic Compressibility and Volumetric Properties of [Difurylmethane plus (Acetonitrile or Propionitrile or Benzonitrile)] Binary Mixtures at 298.15 K

被引:0
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作者
Ddamba, Wilfred A. A. [1 ]
机构
[1] Univ Botswana, Dept Chem, Gaborone, Botswana
关键词
Difurylmethane; Acetonitrile; Propionitrile; Benzonitrile; Binary mixtures; Excess molar volume; Isentropic; compressibilities; Excess isentropic compressibilities; Dipole-dipole interactions; ACETONITRILE; EXCESS; TEMPERATURE; SPEEDS;
D O I
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Densities (rho) and speed sound (u) of binary systems of difurylmethane (DFM) with acetonitirile (ACN), benzonitrile (BCN) or propionitrile (PCN) have been measured over the entire composition range at 298.15 K and atmospheric pressure. Excess isentropic compressibilities (K-s(E)), and excess ultrasonic speeds, u(E), of [DFM + (ACN or BCN or PCN)] and excess molar volumes (V-m(E)), of [DFM + (BCN or PCN)] binary systems were determined and correlated by the Redlich-Kister equation. The results have been discussed in terms of possible intermolecular interactions and structural effects.
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页码:5205 / 5210
页数:6
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