Electrochemical Deoxygenation of Primary Alcohols

被引:22
|
作者
Lam, Kevin [1 ]
Marko, Istvan E. [1 ]
机构
[1] Catholic Univ Louvain, Dept Chem, B-1348 Louvain, Belgium
关键词
deoxygenation; electrochemical; esters; reduction; free radicals; SOLID-SUPPORTED BASES; ACID;
D O I
10.1055/s-0031-1290778
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Direct electrolysis of primary alcohols, in the presence of methyl toluate, leads smoothly to the formation of the corresponding deoxygenated product in high yield.
引用
收藏
页码:1235 / 1239
页数:5
相关论文
共 50 条
  • [21] A NEW METHOD FOR THE DEOXYGENATION OF TERTIARY AND SECONDARY ALCOHOLS
    DOLAN, SC
    MACMILLAN, J
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (22) : 1588 - 1589
  • [22] Reductive deoxygenation of alcohols by PMHS assisted by iodide
    Ye, Xiang
    Zhang, Jihong
    Yang, Haikuan
    Yang, Shusheng
    Ren, Qiong
    Peng, Yang
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2025, 23 (12) : 2878 - 2882
  • [23] Catalytic reductive coupling and deoxygenation of activated alcohols
    Kasner, Gabrielle
    Boucher-Jacobs, Camille
    Nicholas, Kenny
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2016, 251
  • [24] A new clean technology for the deoxygenation of alcohols.
    Booker-Milburn, KI
    Elghamry, N
    Meadows, JD
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1998, 216 : U483 - U483
  • [25] Unusual, selective, reductive, deoxygenation of cyclopentenone alcohols
    Bavikar, Suhas R.
    Lasonkar, Trupti P.
    Chavan, Subhash P.
    Borate, Hanumant B.
    TETRAHEDRON LETTERS, 2014, 55 (38) : 5241 - 5243
  • [26] Radical deoxygenation of tertiary alcohols via trifluoroacetates
    Kim, JG
    Cho, DH
    Jang, DO
    TETRAHEDRON LETTERS, 2004, 45 (15) : 3031 - 3033
  • [27] Copper-Catalyzed Reduction of Alkyl Triflates and Iodides: An Efficient Method for the Deoxygenation of Primary and Secondary Alcohols
    Dang, Hester
    Cox, Nick
    Lalic, Gojko
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (03) : 752 - 756
  • [28] Radical deoxygenation of alcohols via their trifluoroacetate derivatives with diphenylsilane
    Jang, DO
    Kim, JG
    Cho, DH
    Chung, CM
    TETRAHEDRON LETTERS, 2001, 42 (06) : 1073 - 1075
  • [29] Visible light photoredox-catalyzed deoxygenation of alcohols
    Rackl, Daniel
    Kais, Viktor
    Kreitmeier, Peter
    Reiser, Oliver
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2014, 10 : 2157 - 2165
  • [30] Metal-catalyzed selective deoxygenation of diols to alcohols
    Schlaf, M
    Ghosh, P
    Fagan, PJ
    Hauptman, E
    Bullock, RM
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2001, 40 (20) : 3887 - +