Visible-Light-Induced Beckmann Rearrangement by Organic Photoredox Catalysis

被引：30

作者：

Tang, Li ^{[1
]}

Wang, Zhi-Lv ^{[1
]}

Wan, Hai-Lan ^{[1
]}

He, Yan-Hong ^{[1
]}

Guan, Zhi ^{[1
]}

机构：

[1] Southwest Univ, Sch Chem & Chem Engn, Key Lab Appl Chem Chongqing Municipal, Chongqing 400715, Peoples R China

来源：

ORGANIC LETTERS | 2020年 / 22卷 / 15期

基金：

中国国家自然科学基金;

关键词：

BOND FORMATION; KETOXIMES; MILD; LACTAMS; OXIMES; AMIDES;

D O I：

10.1021/acs.orglett.0c02168

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A facile and general strategy for efficient direct conversion of oximes to amides using an inexpensive organic photocatalyst and visible light is described. This radical Beckmann rearrangement can be performed under mild conditions. Various alkyl aryl ketoximes and diaryl ketoximes can be effectively converted into the corresponding amides in excellent yields.

引用

页码：6182 / 6186

页数：5

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