Synthesis of imino-C-disaccharides related to sucrose

被引:4
|
作者
La Ferla, B [1 ]
Cipolla, L [1 ]
Peri, F [1 ]
Nicotra, F [1 ]
机构
[1] Univ Milano Bicocca, Dept Biotechnol & Biosci, I-20126 Milan, Italy
关键词
D O I
10.1081/CAR-100108281
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
Stabilised ylides 1 and 10, prepared from perbenzylated and peracetylated allyl C-glucopyranosides, respectively, were reacted with differently protected D-serinal; osmylation of the obtained alpha,beta -unsaturated ketones 3 and 12, followed by intramolecular reductive amination, afforded different imino-C-disaccharides 14, 15, 18, and 19 related to sucrose.
引用
收藏
页码:667 / 680
页数:14
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