Layered (ethylenediamine-κ2N,N′)-cobalt(II) molybdate(VI)

被引：5
|
作者：
Lin, BZ [1 ]
机构：
[1] Huaqiao Univ, Inst Mat Phys Chem, Quanzhou 362011, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2002年 / 58卷 / 04期
关键词：
D O I：
10.1107/S0108270102003864
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The structure of poly[[ehtylenediamine-kappa(2)N,N')cobalt(II)]-mu-tetraoxomolybdato(VI)], [Co(C2H8N2)MoO4](n) or [CoMoO4(C2H8N2)](n), is composed of puckered layers constructed from MoO4 tetrahedra and CoN2O4 octahedra, wit the ethylenediamine ligand coordinated to the Co atom in a cis fashion. Each pair of cobalt sites forms a binuclear edge-sharing unit through a [Co2O2} interaction. The binuclear octahedral units are interconnected through the bridging MoO4 tetrahedra into a layer structure.
引用
收藏
页码：M261 / M263
页数：3
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