Synthesis of new (+)-usnic acid derivatives with the flavone structure

被引：4

作者：

Sokolov, D. N. ^{[1
]}

Rakhmanova, M. E. ^{[2
]}

Luzina, O. A. ^{[1
]}

Shernyukov, A. V. ^{[1
]}

Salakhutdinov, N. F. ^{[1
]}

机构：

[1] Russian Acad Sci, NN Vorozhtsov Novosibirsk Inst Organ Chem, Siberian Branch, Novosibirsk 630090, Russia

[2] Novosibirsk Natl Res State Univ, Novosibirsk 630090, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2013年 / 62卷 / 01期

关键词：

(+)-usnic acid; chalcones; flavonoids;

D O I：

10.1007/s11172-013-0031-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of a chalcone derivative (synthesized earlier from usnic acid) with various oxidants (hydrogen peroxide, tert-butyl hydroperoxide, and dichlorodicyanobenzoquinone) gave new flavonols, dihydroflavonols, and flavones. Treatment of the starting chalcone with a nucleophilic reagent (NH2NH2 center dot H2O) afforded a dihydropyrazole-containing derivative.

引用

页码：212 / 216

页数：5

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