A Simple Chemical Route toward Monodisperse Iron Carbide Nanoparticles Displaying Tunable Magnetic and Unprecedented Hyperthermia Properties

被引:167
|
作者
Meffre, Anca [1 ]
Mehdaoui, Boubker [1 ]
Kelsen, Vinciane [1 ]
Fazzini, Pier Francesco [1 ]
Carrey, Julian [1 ]
Lachaize, Sebastien [1 ]
Respaud, Marc [1 ]
Chaudret, Bruno [1 ]
机构
[1] Univ Toulouse, INSA, Lab Phys & Chim Nano Objets, F-31077 Toulouse, France
关键词
Magnetic nanoparticles; iron carbides; iron; core/shell; hyperthermia; organometallic chemistry; SUPERLATTICES; STABILIZATION; SIZE; FE;
D O I
10.1021/nl302160d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report a tunable organometallic synthesis of monodisperse iron carbide and core/shell iron/iron carbide nanoparticles displaying a high magnetization and good air-stability. This process based on the decomposition of Fe(CO)(5) on Fe(0) seed:, allows the control of the amount of carbon diffused and therefore the tuning of nanoparticles magnetic anisotropy. This results in unprecedented hyperthermia properties at moderate magnetic fields, in the range of medical treatments.
引用
收藏
页码:4722 / 4728
页数:7
相关论文
共 50 条
  • [31] Structure and magnetic properties of iron nanoparticles synthesized by chemical vapor condensation
    Lee, DH
    Jang, TS
    Lee, DW
    Kim, BK
    PHYSICA STATUS SOLIDI A-APPLICATIONS AND MATERIALS SCIENCE, 2004, 201 (08): : 1930 - 1933
  • [32] Dendron based antifouling, MRI and magnetic hyperthermia properties of different shaped iron oxide nanoparticles
    Cotin, G.
    Blanco-Andujar, C.
    Nguyen, D-V
    Affolter, C.
    Boutry, S.
    Boos, A.
    Ronot, P.
    Uring-Lambert, B.
    Choquet, P.
    Zorn, P. E.
    Mertz, D.
    Laurent, S.
    Muller, R. N.
    Meyer, F.
    Flesch, D. Felder
    Begin-Colin, S.
    NANOTECHNOLOGY, 2019, 30 (37)
  • [33] The controllable magnetic properties of Fe3N nanoparticles synthesized by a simple urea route
    Lei, Xiang
    Wang, Jinliang
    Peng, Ruzheng
    Wang, Wei
    MATERIALS RESEARCH BULLETIN, 2020, 122
  • [34] Microstructure and Magnetic Properties of Iron Oxide Nanoparticles Prepared by Wet Chemical Method
    Satula, D.
    Kalska-Szostko, B.
    Szymanski, K.
    Dobrzynski, L.
    Kozubowski, J.
    ACTA PHYSICA POLONICA A, 2008, 114 (06) : 1615 - 1621
  • [35] Photocatalytic, optical and magnetic properties of Fe-doped ZnO nanoparticles prepared by chemical route
    Kumar, Khanesh
    Chitkara, Mansi
    Sandhu, Inderjit Singh
    Mehta, D.
    Kumar, Sanjeev
    JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 588 : 681 - 689
  • [36] Structure and magnetic properties of Ti1-xCoxO2 nanoparticles prepared by chemical route
    Sharma, Sunil
    Thakur, Nagesh
    Kotnala, R. K.
    Verma, Kuldeep Chand
    JOURNAL OF CRYSTAL GROWTH, 2011, 321 (01) : 19 - 23
  • [37] Synthesis and Magnetic Properties of Nearly Monodisperse CoFe2O4 Nanoparticles Through a Simple Hydrothermal Condition
    Li, Xing-Hua
    Xu, Cai-Ling
    Han, Xiang-Hua
    Qiao, Liang
    Wang, Tao
    Li, Fa-Shen
    NANOSCALE RESEARCH LETTERS, 2010, 5 (06): : 1039 - 1044
  • [38] Synthesis and Magnetic Properties of Nearly Monodisperse CoFe2O4Nanoparticles Through a Simple Hydrothermal Condition
    Xing-Hua Li
    Cai-Ling Xu
    Xiang-Hua Han
    Liang Qiao
    Tao Wang
    Fa-Shen Li
    Nanoscale Research Letters, 5
  • [39] Comprehensive structural and magnetic properties of iron oxide nanoparticles synthesized through chemical routes
    Ghosh, Anamika
    Srinivas, Veeturi
    Sundara, Ramaprabhu
    JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 818
  • [40] Iron/silicon carbide composites with tunable high-frequency magnetic and dielectric properties for potential electromagnetic wave absorption
    Tong Gao
    Huawei Rong
    Khaled H. Mahmoud
    Jiachang Ruan
    Salah M. El-Bahy
    Abeer A. Faheim
    Yixing Li
    Mina Huang
    Mohamed A. Nassan
    Rongzhi Zhao
    Advanced Composites and Hybrid Materials, 2022, 5 : 1158 - 1167