Development of flame retardant phosphorus- and silicon-containing polybenzoxazines

被引：38
|
作者：
Sponton, M. [1 ]
Ronda, J. C. [1 ]
Galia, M. [1 ]
Cadiz, V. [1 ]
机构：
[1] Univ Rovira & Virgili, Dept Quim Analit & Quim Organ, Tarragona 43007, Spain
来源：
POLYMER DEGRADATION AND STABILITY | 2009年 / 94卷 / 02期
关键词：
Benzoxazine; Phosphorous-containing epoxy resin; Silicon-containing epoxy resin; Thermal stability; Flame retardance; BENZOXAZINE MONOMERS; DIGLYCIDYL ETHER; TERNARY-SYSTEMS; BISPHENOL-A; EPOXY; RESINS; POLYMERIZATION; THERMOSETS;
D O I：
10.1016/j.polymdegradstab.2008.11.017
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The copolymerisation of benzoxazine of bisphenol A and diglycidyl ether of (2,5-dihydroxyphenyl)diphenyl phosphine oxide or diglycidyloxymethylphenylsilane has been Studied. In all samples the molar ratio of the benzoxazine-epoxy system was varied to achieve different Phosphorus or Silicon contents. Their thermal, dynamic-mechanical and flame retardant properties were evaluated. The high limiting oxygen index Values confirmed that the phosphorus-containing benzoxazine-epoxy resins are effective flame retardants, but no efficiency of silicon oil flame retardation was observed. (C) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：145 / 150
页数：6
相关论文
共 50 条
  • [1] Halogen-free flame retardant epoxy resins from hybrids of phosphorus- or silicon-containing epoxies with an amine resin
    Liu, Ying-Ling
    Chang, Gung-Pei
    Wu, Chuan-Shao
    [J]. JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (02) : 1071 - 1077
  • [2] Preparation, thermal properties and flame retardancy of phosphorus- and silicon-containing epoxy resins
    Sponton, M.
    Mercado, L. A.
    Ronda, J. C.
    Galia, M.
    Cadiz, V.
    [J]. POLYMER DEGRADATION AND STABILITY, 2008, 93 (11) : 2025 - 2031
  • [3] Synthesis of a phosphorus- and nitrogen-containing flame retardant and the fabrication of flame retardant cotton
    Liu, Yansong
    Zhang, Jiayue
    Ren, Yuanlin
    Zhang, Guoli
    Liu, Xiaohui
    [J]. TEXTILE RESEARCH JOURNAL, 2022, 92 (19-20) : 3426 - 3442
  • [4] Synthesis and characterization of phosphorus- and silicon-containing flame-retardant curing agents and a study of their effect on thermal properties of epoxy resins
    Agrawal, Seema
    Narula, Anudeep Kumar
    [J]. JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, 2014, 11 (04) : 631 - 637
  • [5] Synthesis and characterization of phosphorus- and silicon-containing flame-retardant curing agents and a study of their effect on thermal properties of epoxy resins
    Seema Agrawal
    Anudeep Kumar Narula
    [J]. Journal of Coatings Technology and Research, 2014, 11 : 631 - 637
  • [6] Mechanistic Study of the Flame Retardancy of Epoxy Resin With a Novel Phosphorus and Silicon-Containing Flame Retardant
    Wang, Jiangbo
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE PART B-PHYSICS, 2020, 59 (07): : 479 - 489
  • [7] Comparative study on flame retardancy and thermal degradation of phosphorus- and silicon-containing epoxy resin composites
    Ka Zhang
    Min-Min Shen
    Kun Wu
    Hai-Feng Liu
    Yankui Zhang
    [J]. Journal of Polymer Research, 2011, 18 : 2061 - 2070
  • [8] Comparative study on flame retardancy and thermal degradation of phosphorus- and silicon-containing epoxy resin composites
    Zhang, Ka
    Shen, Min-Min
    Wu, Kun
    Liu, Hai-Feng
    Zhang, Yankui
    [J]. JOURNAL OF POLYMER RESEARCH, 2011, 18 (06) : 2061 - 2070
  • [9] Flame retardant and hydrophobic cotton using a unique phosphorus–nitrogen–silicon-containing coating
    Yu-Ting Yang
    Jia-Li Huang
    Xin Wang
    Jaime Grunlan
    Lei Song
    Yuan Hu
    [J]. Cellulose, 2022, 29 : 8473 - 8488
  • [10] A Novel Phosphorus/Silicon-Containing Flame Retardant—Functionalized Graphene Nanocomposite: Preparation, Characterization and Flame Retardancy
    Jiangbo Wang
    [J]. Russian Journal of Applied Chemistry, 2020, 93 : 1931 - 1939
12345