Preparation, thermal properties and flame retardancy of phosphorus- and silicon-containing epoxy resins

被引：95
|
作者：
Sponton, M. [1 ]
Mercado, L. A. [1 ]
Ronda, J. C. [1 ]
Galia, M. [1 ]
Cadiz, V. [1 ]
机构：
[1] Univ Rovira & Virgili, Dept Quim Analit & Quim Organ, Tarragona 43007, Spain
来源：
POLYMER DEGRADATION AND STABILITY | 2008年 / 93卷 / 11期
关键词：
Flame retardance; Epoxy; Phosphorus-containing resins; Silicon-containing resins;
D O I：
10.1016/j.polymdegradstab.2008.02.014
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Phosphorus- and silicon-containing epoxy resins were prepared from (2,5-dihydroxyphenyl)diphenyl phosphine oxide (Gly-HPO), diglycidyloxy methylphenyl silane (DGMPS) and 1,4-bis(glycidyloxydimethyl silyl)-benzene (BGDMSB) as epoxy monomers and diaminodiphenylmethane (DDM), bis(3-aminophenyl)methyl phosphine oxide (BAMPO) and bis(4-aminophenoxy)dimethyl silane (APDS) as curing agents. Epoxy resins with different phosphorus and silicon content were obtained. Their thermal, dynamic mechanical and flame retardant properties were evaluated. The high LOI values confirmed that epoxy resins containing hetero-atoms are effective flame retardants, but a synergistic efficiency of phosphorus and silicon on flame retardation was not observed. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2025 / 2031
页数：7
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