Tetrazole compounds .11. Electron impact mass spectrometry of 1-aryl-5-(1-acyl-2-dialkylaminovinyl)-1H-tetrazoles

被引:1
|
作者
Fischer, GW [1 ]
Herrmann, M [1 ]
Moder, M [1 ]
机构
[1] UFZ HELMHOLTZ CTR ENVIRONM RES, D-04318 LEIPZIG, GERMANY
关键词
D O I
10.1002/jhet.5570330346
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The mass spectrometric behaviour of 1-aryl-5-(1-acyl-2-dialkylaminovinyl)-1H-tetrazoles was studied, especially using 1-phenyl-5-(1-benzoyl-2-dimethylaminovinyl)-1H-tetrazole 1 and its D-and N-15-labeled derivatives. All tetrazoles investigated showed a clearly observable molecular ion and underwent as the main fragmentation the elimination of nitrogen followed by a number of various subsequent processes. Besides, primary fragments such as [M-N-3(.)](+) and [M-ArN3](+.) were also observed.
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页码:815 / 823
页数:9
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