Selective olefin epoxidation catalyzed by metallocorroles in ionic liquid medium at room temperature

被引：6
|
作者：
Bose, Suranjana [1 ]
Pariyar, Anand [1 ]
Biswas, Achintesh Narayan [2 ]
Bandyopadhyay, Pinaki [1 ]
机构：
[1] Univ N Bengal, Dept Chem, Raja Rammohunpur 734013, Siliguri, India
[2] Siliguri Coll, Dept Chem, Siliguri 734001, India
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2013年 / 378卷
关键词：
Manganese corrole; Iron corrole; Ionic liquid; Epoxidation; Sodium hypochlorite; MILD OXIDATION; CORROLES; CYCLOPROPANATION; HYDROCARBONS; COMPLEXES; PYRROLE; IRON;
D O I：
10.1016/j.molcata.2013.06.007
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Metallocorrole catalyzed epoxidation of a series of olefins has been carried out in ionic liquid medium at room temperature with different terminal oxidants. The product selectivity achieved in ionic liquid medium shows remarkable improvement over those obtained in common organic solvents. (c) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：179 / 183
页数：5
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