Living anionic polymerization of methyl methacrylate at ambient temperatures in the presence of the tetraphenylphosphonium cation

被引：37
|
作者：
Zagala, AP [1 ]
HogenEsch, TE [1 ]
机构：
[1] UNIV SO CALIF,LOKER HYDROCARBON RES INST,DEPT CHEM,LOS ANGELES,CA 90089
来源：
MACROMOLECULES | 1996年 / 29卷 / 08期
关键词：
D O I：
10.1021/ma951405k
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This work demonstrates that the anionic polymerization of methyl methacrylate (MMA) in the presence of Ph4P+ at ambient temperatures is capable of producing narrow molecular weight distribution (MWD) poly(methyl methacrylate) (PMMA) with a reasonable degree control. This new polymerization method has potential for the synthesis of PMMA, other polyacrylates, and their block copolymers at ambient temperatures.
引用
收藏
页码：3038 / 3039
页数：2
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