Living anionic polymerization of methyl methacrylate at ambient temperatures in the presence of the tetraphenylphosphonium cation

被引：37
|
作者：
Zagala, AP [1 ]
HogenEsch, TE [1 ]
机构：
[1] UNIV SO CALIF,LOKER HYDROCARBON RES INST,DEPT CHEM,LOS ANGELES,CA 90089
来源：
MACROMOLECULES | 1996年 / 29卷 / 08期
关键词：
D O I：
10.1021/ma951405k
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This work demonstrates that the anionic polymerization of methyl methacrylate (MMA) in the presence of Ph4P+ at ambient temperatures is capable of producing narrow molecular weight distribution (MWD) poly(methyl methacrylate) (PMMA) with a reasonable degree control. This new polymerization method has potential for the synthesis of PMMA, other polyacrylates, and their block copolymers at ambient temperatures.
引用
收藏
页码：3038 / 3039
页数：2
相关论文
共 50 条
  • [1] Anionic polymerization of (meth)acrylates in the presence of tetraphenylphosphonium cation.
    Dimov, DK
    HogenEsch, TE
    Zagala, AP
    Muller, AHE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1996, 212 : 309 - POLY
  • [2] Living anionic polymerization of methyl methacrylate in the presence of polydentate dilithium alkoxides
    Baskaran, D
    MACROMOLECULAR CHEMISTRY AND PHYSICS, 2000, 201 (08) : 890 - 895
  • [3] Living anionic polymerization of lauryl methacrylate and synthesis of block copolymers with methyl methacrylate
    Raghunadh, V
    Baskaran, D
    Sivaram, S
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2004, 42 (04) : 875 - 882
  • [4] ANIONIC-POLYMERIZATION OF METHYL-METHACRYLATE IN THE PRESENCE OF PIPERIDINE
    KOLAR, A
    TREKOVAL, J
    VLCEK, P
    JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1978, A12 (05): : 757 - 768
  • [5] ANIONIC POLYMERIZATION OF METHYL-METHACRYLATE IN PRESENCE OF PARA BENZOQUINONE
    VLCEK, P
    TREKOVAL, J
    COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1972, 37 (06) : 1918 - &
  • [6] Kinetic investigation on metal free anionic polymerization of methyl methacrylate using tetraphenylphosphonium as the counterion in tetrahydrofuran
    Baskaran, D
    Muller, AHE
    MACROMOLECULES, 1997, 30 (07) : 1869 - 1874
  • [7] Living Anionic Polymerization of N,N–Dimethylacrylamide and Copolymerization with Methyl Methacrylate in the presence of Bulky Aluminum Phenoxide
    Tatsuki Kitayama
    Ken-ichi Katsukawa
    Polymer Bulletin, 2004, 52 : 117 - 124
  • [8] Anionic living polymerization of alkyl methacrylate at ambient temperature and its mechanism research
    Li, Zheng
    Chen, Jianding
    Zou, Guijin
    Zhang, Tongyuan
    Wei, Dafu
    Xu, Xiang
    Guan, Yong
    Zheng, Anna
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2019, 57 (10) : 1130 - 1139
  • [9] Living anionic polymerization of N,N-dimethylacrylamide and copolymerization with methyl methacrylate in the presence of bulky aluminum phenoxide
    Kitayama, T
    Katsukawa, K
    POLYMER BULLETIN, 2004, 52 (02) : 117 - 124
  • [10] MECHANISM OF ANIONIC-POLYMERIZATION OF METHYL-METHACRYLATE IN THE PRESENCE OF ALUMINUM ALKYLS
    SCHLAAD, H
    MULLER, AHE
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 208 : 500 - POLY
12345