Sulfated tungstate catalyzed selective N-monoalkylation of primary amines with alcohol

被引：24

作者：

Pathare, Sagar P. ^{[1
]}

Akamanchi, Krishnacharya G. ^{[1
]}

机构：

[1] Inst Chem Technol, Dept Pharmaceut Sci & Technol, Bombay 400019, Maharashtra, India

来源：

APPLIED CATALYSIS A-GENERAL | 2013年 / 452卷

关键词：

N-monoalkylation; Sulfated tungstate; Heterogeneous catalysis; Amines; Alcohol; BORROWING HYDROGEN; HETEROAROMATIC AMINES; BENZYL ALCOHOLS; ALKYLATION; SULFONAMIDES; AMINATION; SUBSTITUTION; AMIDATION; GREEN;

D O I：

10.1016/j.apcata.2012.11.017

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We have developed an environmentally benign protocol for N-monoalkylation of primary amines with alcohols using sulfated tungstate as heterogeneous catalyst. Elimination of formation of overalkylated amines as by-products, use of alcohols as alkylating agent has resulted in high atom-economy transformation. In addition efficient, mild reaction conditions, easy product isolation and reusability of the catalyst are attractive features. The developed protocol has been successfully applied for N-monoalkylation of aromatic as well aliphatic amines with different alcohols. (c) 2012 Elsevier B.V. All rights reserved.

引用

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页码：29 / 33

页数：5

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