Hydrogenation of arenes, nitroarenes, and alkenes catalyzed by rhodium nanoparticles supported on natural nanozeolite clinoptilolite

被引：19
|
作者：
Baghbanian, Seyed Meysam [1 ]
Farhang, Maryam [2 ]
Vandat, Seyed Mohammad [1 ]
Tajbakhsh, Mahmood [3 ]
机构：
[1] Islamic Azad Univ, Ayatollah Amoli Branch, Dept Chem, Amol, Iran
[2] Islamic Azad Univ, Amol Branch, Young Researchers & Elite Club, Amol, Iran
[3] Univ Mazandaran, Fac Chem, Babol Sar 47415, Iran
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2015年 / 407卷
关键词：
Rhodium nanoparticles; Nanozeolite; Hydrogenation; Clinoptilolite; NONAQUEOUS IONIC LIQUIDS; CARBON NANOTUBES; RH; NANOCATALYSTS; LIGANDS; WATER; EFFICIENT; RUTHENIUM; BENZENE; OLEFINS;
D O I：
10.1016/j.molcata.2015.06.029
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Nanozeolite clinoptilolite supported rhodium nanoparticles (Rh/NZ-CP) has been prepared and characterized by a variety of techniques, including XRD, BET, TEM, EDX, ICP-OES and XPS analysis. This nanomaterial contains 2 wt% Rh in the range of 5-20 nm metallic nanoparticles distributed on nanozeolite. The catalytic performance of Rh/NZ-CP was evaluated by the hydrogenation of arenes, nitroarenes, and alkenes under moderate reaction conditions. The prepared nanocatalyst can be facilely recovered and reused many times without significant decrease in activity and selectivity. The high catalytic activity, thermal stability and reusability, simple recovery and eco-friendly nature make present catalyst as a unique catalytic system, which is particularly attractive in green chemistry. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码：128 / 136
页数：9
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