Synthesis, Structure, and Magnetic Properties of a New Selenite Compound CdNi(SeO3)2(H2O2)2

被引：0
|
作者：
Li Jin-Yang [1 ,2 ]
Wang Lin [2 ]
Zhao Zhi-Ying [2 ]
He Zhang-Zhen [2 ]
机构：
[1] Fuzhou Univ, Coll Chem, Fuzhou 350108, Peoples R China
[2] Chinese Acad Sci, State Key Lab Struct Chem, Fujian Inst Res Struct Mater, Fuzhou 350002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2020年 / 39卷 / 09期
基金：
中国国家自然科学基金;
关键词：
magnetic; crystal structure; selenite; CRYSTAL-STRUCTURE;
D O I：
10.14102/j.cnki.0254-5861.2011-2646
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new selenite compound CdNi(SeO3)(2)(H2O)(2) has been obtained by a conventional hydrothermal method. This compound crystallizes in monoclinic system of space group C2/c, which exhibits a layer structure built by NiO6 octahedra and SeO3 trigonal pyramids running along the a-axis. The layers show a unique eight-rings hole network. The compound is stable at room temperature while the loss of H2O molecules happens with heating above 523 K. Magnetic measurements indicate that CdNi(SeO3)(2)(H2O)(2) is an antiferromagnet and possesses an antiferromagnetic ordering at T-N = 15 K.
引用
收藏
页码：1694 / 1698
页数：5
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