Revisiting the reaction of hydroxyl radicals with vicinal diols in water

被引：12

作者：

Jiang, Dong ^{[1
]}

Barata-Vallejo, Sebastian ^{[2
]}

Golding, Bernard T. ^{[1
]}

Ferreri, Carla ^{[2
]}

Chatgilialoglu, Chryssostomos ^{[2
]}

机构：

[1] Newcastle Univ, Sch Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

[2] CNR, ISOF, I-40129 Bologna, Italy

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2012年 / 10卷 / 05期

关键词：

AQUEOUS-SOLUTION; REARRANGEMENTS; ANTIOXIDANTS; MECHANISMS; GLYCOL;

D O I：

10.1039/c1ob06538f

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The carbonyl products of the reactions of hydroxyl radicals with three vicinal diols (ethane-1,2-diol, propane-1,2-diol and butane-2,3-diol) have been identified and quantified. Hydroxyl radicals were produced by gamma-radiolysis of N2O-saturated aqueous solutions. The reactions result in the formation of alkoxyl radicals (similar to 15%) followed by beta-fragmentation, and alpha-hydroxyl alkyl radicals that undergo H2O elimination. The latter process is part of a radical chain reaction at higher diol concentrations.

引用

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页码：1102 / 1107

页数：6

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