Uniform hierarchical MoO2/carbon spheres with high cycling performance for lithium ion batteries

被引：64

作者：

Zhang, Hao-Jie ^{[1
]}

Wu, Tian-Hao ^{[1
]}

Wang, Kai-Xue ^{[1
]}

Wu, Xue-Yan ^{[2
]}

Chen, Xiao-Ting ^{[1
]}

Jiang, Yan-Mei ^{[1
]}

Wei, Xiao ^{[1
]}

Chen, Jie-Sheng ^{[1
]}

机构：

[1] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China

[2] Shanghai Jiao Tong Univ, Sch Mat Sci & Engn, Shanghai 200240, Peoples R China

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2013年 / 1卷 / 39期

基金：

中国国家自然科学基金;

关键词：

STORAGE PERFORMANCE; ANODE MATERIALS; MOO2; NANOBELTS; NANOTUBES;

D O I：

10.1039/c3ta12566a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Uniform hierarchical MoO2/C spheres have been prepared through calcination of a MoO3/resin precursor generated via a simple hydrothermal method in the presence of resorcinol, formaldehyde and (NH4)(6)Mo7O24 center dot 4H(2)O. The carbon spheres formed in situ by the carbonization of resorcinol-formaldehyde resin in a N-2 atmosphere reduce MoO3 into MoO2 nanoparticles. The MoO2/C spheres have been characterized by XRD, SEM, HR-TEM and TGA. Used as an anode material, these spheres exhibit not only good rate capability but also high cycling performance. These hierarchical MoO2/C spheres are a promising anode material for high performance lithium ion batteries.

引用

页码：12038 / 12043

页数：6

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