Diaqua( 2,5-di-4-pyridyl-1,3,4-thiadiazole-kN2)bis(thiocyanato-kN)-nickel(II) dihydrate

被引：2
|
作者：
Yang, Ming-Hua [1 ]
机构：
[1] Lishui Univ, Dept Chem, Lishui 323000, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808030444
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title mononuclear complex, [Ni(NCS)(2)(C12H8N4S)(2)- H2O)(2)] center dot 2H(2)O, the Ni-II atom is located on an inversion center and is octahedrally coordinated by four N atoms from two 2,5-di- 4-pyridyl-1,3,4-thiadiazole ( bpt) ligands and two thiocyanate molecules forming the equatorial plane; the axial positions are occupied by two O atoms of coordinated water molecules. O - H center dot center dot center dot O, O - H center dot center dot center dot N and O - H center dot center dot center dot S hydrogen bonds, involving the uncoordinated water molecules, result in the formation of a sheet structure developing parallel to (021).
引用
收藏
页码：M1331 / U3054
页数：10
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