Assessment of the low-temperature nonoxidative activation of methane over H-galloaluminosilicate (MFI) zeolite:: A C-13 labelling investigation

被引：24

作者：

Naccache, CM ^{[1
]}

Mériaudeau, P ^{[1
]}

Sapaly, G ^{[1
]}

Van Tiep, L ^{[1
]}

Taârit, YB ^{[1
]}

机构：

[1] CNRS, Inst Rech Catalyse, Convent UCB Lyon 2, F-69626 Villeurbanne, France

来源：

JOURNAL OF CATALYSIS | 2002年 / 205卷 / 01期

关键词：

methane activation; isotopic labelling; Ga-MFI; aromatisation;

D O I：

10.1006/jcat.2001.3376

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Careful investigation of the conversion of various mixtures of propene and methane or ethene and methane over H-galloaluminosilicate (MFI) zeolite under a variety of conditions showed that methane is not inserted into the products. The use of C-13-labelled methane confirmed the absence of methane activation under the reported conditions. (C) 2002 Elsevier Science.

引用

页码：217 / 220

页数：4

共 32 条

[31] LOW-TEMPERATURE SINGLE-CRYSTAL X-RAY-DIFFRACTION, H-1 AND C-13 SOLID-STATE NMR AND N-14 NQR STUDIES OF 1,8-BIS(DIMEAHYLAMINO)NAPHTHALENE
WOZNIAK, K
HE, HY
KLINOWSKI, J
NOGAJ, B
LEMANSKI, D
HIBBS, DE
HURSTHOUSE, MB
HOWARD, ST
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1995, 91 (21): : 3925 - 3932
[32] LOW-TEMPERATURE H-1, C-13, SE-77, AND TE-125 NMR-STUDIES ON THE APICAL-APICAL LIGAND-EXCHANGE VIA THE HYPERVALENT TELLURIUM AND SELENIUM ATE COMPLEXES [10-M-3(C3), M=SE, TE] IN THE REACTIONS OF DIARYL TELLURIDES AND SELENIDES WITH ARYLLITHIUM REAGENTS
MASUTOMI, Y
FURUKAWA, N
ERATA, T
HETEROATOM CHEMISTRY, 1995, 6 (01) : 19 - 27

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