Assessment of the low-temperature nonoxidative activation of methane over H-galloaluminosilicate (MFI) zeolite:: A C-13 labelling investigation

被引：24

作者：

Naccache, CM ^{[1
]}

Mériaudeau, P ^{[1
]}

Sapaly, G ^{[1
]}

Van Tiep, L ^{[1
]}

Taârit, YB ^{[1
]}

机构：

[1] CNRS, Inst Rech Catalyse, Convent UCB Lyon 2, F-69626 Villeurbanne, France

来源：

JOURNAL OF CATALYSIS | 2002年 / 205卷 / 01期

关键词：

methane activation; isotopic labelling; Ga-MFI; aromatisation;

D O I：

10.1006/jcat.2001.3376

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Careful investigation of the conversion of various mixtures of propene and methane or ethene and methane over H-galloaluminosilicate (MFI) zeolite under a variety of conditions showed that methane is not inserted into the products. The use of C-13-labelled methane confirmed the absence of methane activation under the reported conditions. (C) 2002 Elsevier Science.

引用

页码：217 / 220

页数：4

共 32 条

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Choudhary, VR
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JOURNAL OF CATALYSIS, 2002, 205 (02) : 398 - 403
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BROWNSTEIN, S
JOURNAL OF MAGNETIC RESONANCE, 1978, 29 (02) : 207 - 211
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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (38) : 12021 - 12032
[8] 1H and 13C MAS NMR studies of light alkanes activation over MFI zeolite modified by Zn vapour
Kolyagin, Yuriy G.
Ivanova, Irina I.
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SOLID STATE NUCLEAR MAGNETIC RESONANCE, 2009, 35 (02) : 104 - 112
[9] Low-temperature activation of methane over rare earth metals promoted Zn/HZSM-5 zeolite catalysts in the presence of ethylene
Zhang, Hengqiang
Kong, Aiguo
Ding, Yongjie
Dai, Chengyong
Shan, Yongkui
JOURNAL OF NATURAL GAS CHEMISTRY, 2011, 20 (03): : 243 - 248
[10] Low-temperature activation of methane over rare earth metals promoted Zn/HZSM-5 zeolite catalysts in the presence of ethylene
Hengqiang Zhang
Journal of Energy Chemistry, 2011, 20 (03) : 243 - 248

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