Air- and Water-Stable Gold-Coated Gadolinium Metal Nanocrystals

被引：15
|
作者：
Yan, Chao [1 ]
Wagner, Michael J. [1 ]
机构：
[1] George Washington Univ, Washington, DC 20052 USA
来源：
NANO LETTERS | 2013年 / 13卷 / 06期
关键词：
Lanthanide; magnetic; core-shell; MRI; refrigerant; MAGNETIC-PROPERTIES; NANOPARTICLES; THERAPY;
D O I：
10.1021/nl400720n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Gold-coated gadolinium nanocrystals, with an average diameter of 3.20 +/- 0.35 nm, have been synthesized at ambient temperature by alkalide reduction. Whereas uncoated gadolinium nanoparticles react violently with air and water, the gold coated gadolinium nanocrystals reported here show no reaction even upon long-term exposure. This is the first example of air- and water stable lanthanide metal nanocrystals, which may allow for the development of magnetic and biomedical applications of gadolinium and other lanthanide metal and alloy nanocrystals.
引用
收藏
页码：2611 / 2614
页数：4
相关论文
共 50 条
  • [21] Air- and water-stable Lewis acids: synthesis and reactivity of P-trifluoromethyl electrophilic phosphonium cations
    Fasano, V.
    LaFortune, J. H. W.
    Bayne, J. M.
    Ingleson, M. J.
    Stephan, D. W.
    CHEMICAL COMMUNICATIONS, 2018, 54 (06) : 662 - 665
  • [22] Electrodeposition of Ge, Si and SixGe1-x from an air- and water-stable ionic liquid
    Al-Salman, R.
    El Abedin, S. Zein
    Endres, F.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2008, 10 (31) : 4650 - 4657
  • [23] High proton conduction in an excellent water-stable gadolinium metal-organic framework
    Xing, Xiu-Shuang
    Fu, Zhi-Hua
    Zhang, Ning-Ning
    Yu, Xiao-Qing
    Wang, Ming-Sheng
    Guo, Guo-Cong
    CHEMICAL COMMUNICATIONS, 2019, 55 (09) : 1241 - 1244
  • [24] Electrodeposition of nickel in air- and water-stable 1-butyl-3-methylimidazolium dibutylphosphate ionic liquid
    Zheng, Yu
    Zhou, Xiaorong
    Luo, Yunbai
    Yu, Ping
    RSC ADVANCES, 2020, 10 (28) : 16576 - 16583
  • [25] Use of NMR spectroscopy in the synthesis and characterization of air- and water-stable silicon nanoparticles from porous silicon
    Carter, RS
    Harley, SJ
    Power, PP
    Augustine, MP
    CHEMISTRY OF MATERIALS, 2005, 17 (11) : 2932 - 2939
  • [26] Air- and Water-Resistant Noble Metal Coated Ferromagnetic Cobalt Nanorods
    Lentijo-Mozo, Sergio
    Tan, Reasmey P.
    Garcia-Marcelot, Cecile
    Altantzis, Thomas
    Fazzini, Pier-Francesco
    Hungria, Teresa
    Cormary, Benoit
    Gallagher, James R.
    Miller, Jeffrey T.
    Martinez, Herve
    Schrittwieser, Stefan
    Schotter, Joerg
    Respaud, Marc
    Bals, Sara
    Van Tendeloo, Gustaaf
    Gatel, Christophe
    Soulantica, Katerina
    ACS NANO, 2015, 9 (03) : 2792 - 2804
  • [27] A Convinient Method to Prepare Gold-Coated C60 Nanocrystals
    Masuhara, Akito
    Tan, Zhenquan
    Kasai, Hitoshi
    Nakanishi, Hachiro
    Oikawa, Hidetoshi
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2008, 492 : 262 - 267
  • [28] An Air- and Water-Stable B4N4-Heteropentalene Serving as a Host Material for a Phosphorescent OLED
    Kashida, Junki
    Shoji, Yoshiaki
    Ikabata, Yasuhiro
    Taka, Hideo
    Sakai, Hayato
    Hasobe, Taku
    Nakai, Hiromi
    Fukushima, Takanori
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2021, 60 (44) : 23812 - 23818
  • [29] Aluminium oxidation at high anodic potentials in an AlCl3-containing air- and water-stable ionic liquid solution
    Veder, Jean-Pierre M.
    Horne, Michael D.
    Ruether, Thomas
    Bond, Alan M.
    Rodopoulos, Theo
    ELECTROCHEMISTRY COMMUNICATIONS, 2013, 37 : 68 - 70
  • [30] Underpotential Deposition of Silver on Au(111) from an Air- and Water-Stable Ionic Liquid Visualized by In-Situ STM
    Ehrenburg, Maria R.
    Molodkina, Elena B.
    Broekmann, Peter
    Rudnev, Alexander, V
    CHEMELECTROCHEM, 2019, 6 (04) : 1149 - 1156
12345