Set of Acidic Resin Catalysts To Correlate Structure and Reactivity in Fructose Conversion to 5-Hydroxymethylfurfural

被引：56
|
作者：
Richter, Felix H. [1 ]
Pupovac, Kristina [1 ]
Palkovits, Regina [2 ]
Schueth, Ferdi [1 ]
机构：
[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Germany
[2] Rhein Westfal TH Aachen, D-52056 Aachen, Germany
来源：
ACS CATALYSIS | 2013年 / 3卷 / 02期
基金：
欧洲研究理事会;
关键词：
polymer resin; acid catalyst; biomass conversion; dehydration; cross-linker content; CATIONIC EXCHANGE RESINS; POLYMER NETWORKS; BIOMASS; DEHYDRATION; HYDROCARBONS; SULFONATION; CHEMICALS; XYLOSE; ACTIVATION; SYSTEM;
D O I：
10.1021/cs3007439
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A new synthetic route to acidic polystyrene-co-divinylbenzene resin catalysts allows systematic variation of cross-linker content, porosity, and acid site density. These resins are prepared in the form of powders by nanocasting, and the acid site density and the distribution of the acid sites in the prepared catalysts is controlled by liquid phase sulfonation with adjusted mixtures of sulfuric acid and oleum. This method allows identical synthesis conditions for the entire range of cross-linker content. With this set of model catalysts, the crosslinker content of the resin was found to be the most influential factor for the liquid phase dehydration of fructose to 5-hydroxymethylfurfural.
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页码：123 / 127
页数：5
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